Heteroleptic complexes of Ni(II) with 2,2′-bipyridine and benzoato ligands. Magnetic properties of [Ni(bpy)(Bz)2]
Sign Up to like & getrecommendations! Published in 2021 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2021.120588
Abstract: Abstract Under various experimental conditions seven complexes have been crystallized from the systems Ni(II) – HBz – bpy (HBz = benzoic acid, bpy = 2,2′-bipyridine). The use of freshly prepared Ni(OH)2 as starting reagent leads to isolation of [Ni(bpy)(Bz)2]… read more here.
Keywords: bipyridine benzoato; complexes bipyridine; bpy no3; heteroleptic complexes ... See more keywords
New heteroleptic Zn(II) and Cu(II) complexes with quercetine and N^N ligands
Sign Up to like & getrecommendations! Published in 2018 at "Polyhedron"
DOI: 10.1016/j.poly.2018.03.016
Abstract: Abstract New heteroleptic complexes having the general formula (N^N)MQCl, where N^N = 2,2′-bipyridine or 1,10-phenanthroline, M = Cu(II) or Zn(II) and Q = quercetin were synthesized and characterized by analytical and spectroscopic methods. The complexes are more sensitive to air oxygen… read more here.
Keywords: quercetine ligands; heteroleptic complexes; complexes quercetine; new heteroleptic ... See more keywords
Steric demands in the formation of heteroleptic Cu(I) complexes with α-diimines and triphenylphosphine
Sign Up to like & getrecommendations! Published in 2018 at "Polyhedron"
DOI: 10.1016/j.poly.2018.05.042
Abstract: Abstract The synthesis and the study of the molecular structure of a series of heteroleptic copper(I) compounds with triphenylphosphine and α-diimines presenting a varying degree of bulk at their chelating cite is reported. The most… read more here.
Keywords: demands formation; formation heteroleptic; heteroleptic complexes; complexes diimines ... See more keywords
Lanthanoid Heteroleptic Complexes with Cucurbit[5]uril and Dicarboxylate Ligands: From Discrete Structures to One-Dimensional and Two-Dimensional Polymers.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b02732
Abstract: Lanthanoid heteroleptic complexes with cucurbit[5]uril {Q[5]} and two dicarboxylate ligands, e.g., diglycolic acid (H2DGC) and glutaric acid (H2GT), have been investigated with six new compounds featuring a tetrametallic and dimetallic discrete structures, a one-dimensional (1D)… read more here.
Keywords: heteroleptic complexes; h2o; topology; dgc h2o ... See more keywords
Heteroleptic Ni(II) Complexes Bearing a Bulky Yet Flexible IBiox-6 Ligand: Improved Selectivity in Cross-Electrophile Coupling of Benzyl Chlorides with Aryl Chlorides/Fluorides
Sign Up to like & getrecommendations! Published in 2020 at "Organometallics"
DOI: 10.1021/acs.organomet.0c00515
Abstract: A bisoxazoline-derived NHC known as IBiox-6 reacted smoothly with Ni[P(OEt)3]2Br2 and Ni(PPh3)2Br2 to give the respective heteroleptic Ni(II) complexes Ni(IBiox-6)[P(OEt)3]Br2 (1) and Ni(IBiox-6)(P... read more here.
Keywords: bulky yet; complexes bearing; yet flexible; ibiox ... See more keywords
Heteroleptic Re(CO)2+ and Re(CO)3+ complexes with α-diimines: similarities and differences in their luminescence properties
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DOI: 10.1039/d0ra06262f
Abstract: The photophysical properties of two series of phosphorescent rhenium(I) complexes, [Re(CO)2(N^N)(tpp)2]+ and [Re(CO)3(N^N)(tpp)]+ with carbon monoxide (CO), triphenylphosphine (tpp) and α-diimine (N^N) ligands have been investigated in deoxygenated acetonitrile solution at room temperature and in… read more here.
Keywords: complexes diimines; heteroleptic complexes; luminescence properties; series ... See more keywords