Structural motifs in heteroleptic copper and cadmium selenites
Sign Up to like & getrecommendations! Published in 2018 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2017.05.043
Abstract: Abstract Cu(II) cations in the presence of diamine ligands such as tetramethylethylendiamine (TMEDA) react with Na2SeO3 to produce the heteroleptic selenite copper compound of formula [Cu3(TMEDA)3(SeO3)2(H2O)4](NO3)2. In the cationic moiety two copper atoms are linked… read more here.
Keywords: structural motifs; copper cadmium; copper; heteroleptic copper ... See more keywords
The first tris-heteroleptic copper cage, ligated by germsesquioxanes, 2,2′-bipyridines and 3,5-dimethylpyrazolates. Synthesis, structure and unique catalytic activity in oxidation of alkanes and alcohols with peroxides
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2019.120911
Abstract: Abstract Self-assembly reaction of copper(II) ions and triple set of ligands (phenylgermaniumsesquioxane, 2,2′-bipyridine, 3,5-dimethylpyrazolate) results in the formation of the first example of tris-heteroleptic copper cage product (PhGeO2)10Cu6(2,2′-bipy)2(3,5-Me2Pz)2 (1). The ligation styles of complex’ components… read more here.
Keywords: tris heteroleptic; copper; oxidation; heteroleptic copper ... See more keywords
Heteroleptic Copper(I) Complexes of “Scorpionate” Bis-pyrazolyl Carboxylate Ligand with Auxiliary Phosphine as Potential Anticancer Agents: An Insight into Cytotoxic Mode
Sign Up to like & getrecommendations! Published in 2017 at "Scientific Reports"
DOI: 10.1038/srep45229
Abstract: New copper(I) complexes [CuCl(PPh3)(L)] (1: L = LA = 4-carboxyphenyl)bis(3,5-dimethylpyrazolyl)methane; (2: L = LB = 3-carboxyphenyl)bis(3,5-dimethylpyrazolyl)methane) were prepared and characterised by elemental analysis and various spectroscopic techniques such as FT-IR, NMR, UV–Vis, and ESI-MS. The molecular structures of complexes 1 and 2 were… read more here.
Keywords: copper complexes; dna; heteroleptic copper; complexes scorpionate ... See more keywords
Heteroleptic copper(I) charge-transfer chromophores with panchromatic absorption.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc03873k
Abstract: Four new heteroleptic bis-chelate Cu(I) complexes showing panchromatic visible absorption are described here. With this heteroleptic design, we demonstrate that the energy levels of the spatially separated HOMO and LUMO can be independently and systematically… read more here.
Keywords: copper charge; charge transfer; absorption; heteroleptic copper ... See more keywords
Remote Steric Control of the Tetrahedral Coordination Geometry around Heteroleptic Copper(I) Bis(Diimine) Complexes
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28030983
Abstract: In this study, a series of new heteroleptic copper(I) bis(diimine) complexes are described. Using one highly hindered phenanthroline ligand and a second less-hindered diimine ligand led to unexpected results. Following a two-step one-pot method to… read more here.
Keywords: copper; coordination; diimine; copper bis ... See more keywords