Heteroleptic Cyclometalated NHC Iridium(III) complex with a bulky acetylacetonate: Photophysics of an unexplored class of compounds
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2020.121251
Abstract: Abstract The photophysical properties of heteroleptic cyclometalated NHC iridium(III) complexes with bulky acetylacetonates have previously not been explored. To fill this gap, we prepared a new heteroleptic iridium(III) complex and measured its photophysical properties. We… read more here.
Keywords: iridium iii; cyclometalated nhc; iridium; nhc iridium ... See more keywords
Effects of geometrical isomerism on emissive behaviour of heteroleptic cyclometalated Ir(III) complexes.
Sign Up to like & getrecommendations! Published in 2021 at "Dalton transactions"
DOI: 10.1039/d1dt00783a
Abstract: In this study, we report the emissive properties of a heteroleptic cyclometalated Ir(iii) complex, [Ir(bzq)2(PBO)] (bzqH = benzo[h]quinoline; PBOH = 2-(2-hydroxyphenyl)benzoxazole). The complex, [Ir(C^N)2(N^O)], was synthesised and optically resolved using a chiral column. Two geometrical… read more here.
Keywords: effects geometrical; isomerism emissive; geometrical isomerism; cyclometalated iii ... See more keywords