Thermal-mediated catalyst-free heterolytic cleavage of 3-halooxindoles: rapid access to 3-functionalized-2-oxindoles
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DOI: 10.1039/c8qo01222a
Abstract: Herein a previously unreported catalyst-free SN1 reaction of the 3-halooxindoles to build 3-functionalized-2-oxindoles is described. read more here.
Keywords: mediated catalyst; thermal mediated; heterolytic cleavage; free heterolytic ... See more keywords
Frustration across the periodic table: heterolytic cleavage of dihydrogen by metal complexes
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DOI: 10.1098/rsta.2017.0002
Abstract: This perspective examines frustrated Lewis pairs (FLPs) in the context of heterolytic cleavage of H2 by transition metal complexes, with an emphasis on molecular complexes bearing an intramolecular Lewis base. FLPs have traditionally been associated… read more here.
Keywords: metal; heterolytic cleavage; metal complexes; transition metal ... See more keywords