Articles with "heterometallic cluster" as a keyword



Aggregation of Polybismuthide Anions in a Single Compound Using +Rh-CO Units: Heterometallic Cluster Ions [Rh@Bi10(RhCO)6]3- and [Rh@Bi9(RhCO)5]3.

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Published in 2020 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.0c01074

Abstract: In the presence of the roughly flat sequestering agent, [K(18-crown-6)]+, the reaction of Rh2(CO)4Cl2 with K5Bi4 in ethylenediamine (en) solution at room temperature yielded the heterometallic cluster anion [Rh@Bi10(RhCO)6]3- (1), in which two hitherto unknown… read more here.

Keywords: bi10 rhco; bi9 rhco; cluster; heterometallic cluster ... See more keywords
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Synthesis, Structure, and Spectroscopic Study of Redox-Active Heterometallic Cluster-Based Complexes [Re5MoSe8(CN)6]n.

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Published in 2021 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.1c00763

Abstract: The heterometallic cluster-based compound K5[Re5MoSe8(CN)6] was obtained by high-temperature reaction from a mixture of ReSe2 and MoSe2 in molten potassium cyanide. The redox behavior of the [Re5MoSe8(CN)6]5- cluster anion was studied by cyclic voltammetry in… read more here.

Keywords: heterometallic cluster; structure spectroscopic; cluster based; synthesis structure ... See more keywords
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Organoamine-Directed Assembly of 5p-4f Heterometallic Cluster Substituted Polyoxometalates: Luminescence and Proton Conduction Properties.

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Published in 2021 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.1c02099

Abstract: The assembly of heterometallic cluster substituted polyoxometalates (POMs) remains a great challenge for inorganic synthetic chemistry up to now. Herein, a series of 5p-4f heterometallic cluster substituted POMs were successfully isolated by a facile one-step… read more here.

Keywords: heterometallic cluster; substituted polyoxometalates; chemistry; assembly heterometallic ... See more keywords
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Two rare Cr–Ln (Ln = Dy, Tb) heterometallic cluster substituted polyoxometalates featuring hexameric aggregates: hydrothermal syntheses, crystal structures and magnetic studies

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Published in 2019 at "New Journal of Chemistry"

DOI: 10.1039/c8nj06327c

Abstract: Two hexameric Cr–Ln cluster substituted POMs have been obtained under hydrothermal conditions. They represent the first examples of 3d–4f heterometallic cluster substituted POMs incorporating Cr–Ln clusters. read more here.

Keywords: rare heterometallic; heterometallic cluster; cluster; substituted polyoxometalates ... See more keywords