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Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c01074
Abstract: In the presence of the roughly flat sequestering agent, [K(18-crown-6)]+, the reaction of Rh2(CO)4Cl2 with K5Bi4 in ethylenediamine (en) solution at room temperature yielded the heterometallic cluster anion [Rh@Bi10(RhCO)6]3- (1), in which two hitherto unknown…
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Keywords:
bi10 rhco;
bi9 rhco;
cluster;
heterometallic cluster ... See more keywords
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Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00763
Abstract: The heterometallic cluster-based compound K5[Re5MoSe8(CN)6] was obtained by high-temperature reaction from a mixture of ReSe2 and MoSe2 in molten potassium cyanide. The redox behavior of the [Re5MoSe8(CN)6]5- cluster anion was studied by cyclic voltammetry in…
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Keywords:
heterometallic cluster;
structure spectroscopic;
cluster based;
synthesis structure ... See more keywords
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Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c02099
Abstract: The assembly of heterometallic cluster substituted polyoxometalates (POMs) remains a great challenge for inorganic synthetic chemistry up to now. Herein, a series of 5p-4f heterometallic cluster substituted POMs were successfully isolated by a facile one-step…
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Keywords:
heterometallic cluster;
substituted polyoxometalates;
chemistry;
assembly heterometallic ... See more keywords
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Published in 2019 at "New Journal of Chemistry"
DOI: 10.1039/c8nj06327c
Abstract: Two hexameric Cr–Ln cluster substituted POMs have been obtained under hydrothermal conditions. They represent the first examples of 3d–4f heterometallic cluster substituted POMs incorporating Cr–Ln clusters.
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Keywords:
rare heterometallic;
heterometallic cluster;
cluster;
substituted polyoxometalates ... See more keywords