The metallostibine Os2(CO)8(μ-SbPh): A versatile donor precursor for antimony-containing heterometallic clusters
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2018.01.011
Abstract: Abstract The metallostibine Os 2 (CO) 8 ( μ -SbPh), 2 , acts as a good two-electron donor ligand, reacting readily with Group 8 metal carbonyls to give heterometallic clusters. Specifically, it undergoes ligand substitution… read more here.
Keywords: versatile donor; sbph versatile; heterometallic clusters; metallostibine os2 ... See more keywords
Heterometallic Clusters with Uranium-Metal Bonds Supported by Double-Layer Nitrogen-Phosphorus Ligands.
Sign Up to like & getrecommendations! Published in 2022 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.2c00180
Abstract: ConspectusHeterometallic clusters with M-M bonds have significantly interested chemists because of their attractive structures and synergistic effects in small-molecule activation and catalysis. However, reports of the isolation of heterometallic clusters with uranium-transition metal (U-TM) bonds… read more here.
Keywords: double layer; heterometallic clusters; clusters uranium; activation ... See more keywords
Intermetalloid and Heterometallic Clusters Combining p-Block (Semi)Metals with d- or f-Block Metals.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical reviews"
DOI: 10.1021/acs.chemrev.8b00658
Abstract: Clusters have been the subject of intense investigations since their famous definition launched by Cotton in 1963, and the area has expanded ever since. One obvious development addresses the widening of the definition of what… read more here.
Keywords: transition metal; clusters combining; metal; heterometallic clusters ... See more keywords
Anion-Dependent Assembly of Heterometallic 3d-4f Clusters Based on a Lacunary Polyoxometalate.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b01104
Abstract: A series of heterometallic 3d-4f clusters, formulated as Na17[Ln3(H2O)5NiII(H2O)3(Sb4O4)(SbW9O33)3(NiIIW6O24)(WO2)3(CH3COO)]·(H2O)65 [abbreviated as Ln3Ni2, where Ln = La3+ (1), Pr3+ (2), and Nd3+ (3)], K5Na11[Ln3(H2O)3NiII3(H2O)6(SbW9O33)3(WO4)(CO3)]·(H2O)40 [abbreviated as Ln3Ni3, where Ln = La3+ (4), Pr3+ (5), and Nd3+… read more here.
Keywords: anion dependent; h2o; heterometallic clusters; h2o abbreviated ... See more keywords