From the Design of Innovative Ti‐Pt Heterometallic Complexes to the Development of Highly Anti‐Proliferative Water‐Soluble Cationic Titanocenes
Sign Up to like & getrecommendations! Published in 2024 at "ChemBioChem"
DOI: 10.1002/cbic.202400099
Abstract: Two innovative early/late Ti−Pt‐heterobimetallic complexes were synthesized, characterized, and screened in cell‐based assays using several human (SW480 and MDA‐MB‐231) and murine cancer cell lines (CT26 and EMT6) as well as a non‐cancerous cell line (HMEC).… read more here.
Keywords: heterometallic complexes; design innovative; innovative heterometallic; anti proliferative ... See more keywords
Structural and luminescent properties of homo- and heterometallic complexes of La, Li and Na with 2-(2-benzoxyazol-2-yl)phenolate ligands
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Luminescence"
DOI: 10.1016/j.jlumin.2018.06.046
Abstract: Abstract A series of homo and heterometallic La, Li and Na complexes with 2-(2-benzoxyazol-2-yl)phenolate (L) ligands were synthesized using La[N(SiMe3)2]3 and M[N(SiMe3)2] (M = Li, Na) or La(Cp)3 as starting materials for La2(L)6 (1), La2(L)6(bipy)… read more here.
Keywords: phenolate ligands; heterometallic complexes; homo heterometallic; complexes benzoxyazol ... See more keywords
Synthesis and Reactivity of Triangular Heterometallic Complexes Containing Zn-Zn Bond.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00956
Abstract: This work provides a facile access to a series of triangular [Zn2M] (M = group 10 and 11 metals) clusters. Treatment of Zn-Zn-bonded compounds [LZn-ZnL] (L = CH3C(2,6-iPr2C6H3N)CHC(CH3)(NCH2CH2PR2); R = Ph, iPr) with zero-valent transition-metal… read more here.
Keywords: heterometallic complexes; triangular heterometallic; reactivity triangular; synthesis reactivity ... See more keywords
Rare-earth/zinc heterometallic complexes containing both alkoxy-amino-bis(phenolato) and chiral salen ligands: synthesis and catalytic application for copolymerization of CO2 with cyclohexene oxide.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt00064j
Abstract: Ten rare-earth/zinc heterometallic complexes containing both alkoxy-amino-bis(phenolato) and chiral salen ligands were synthesized from the reactions of alkoxy-amino-bis(phenolato) rare-earth complexes with chiral salen zinc complexes via ligand redistribution and THF disassociation. Six of them were… read more here.
Keywords: zinc; heterometallic complexes; rare earth; alkoxy amino ... See more keywords
Self-assembled heterometallic complexes showing enhanced two-photon absorption and their distribution in living cells
Sign Up to like & getrecommendations! Published in 2021 at "New Journal of Chemistry"
DOI: 10.1039/d0nj05219a
Abstract: Heterometallic binuclear Ru–Pt and trinuclear Zn–Pt complexes were prepared via self-assembly by attaching PtII-tpy (tpy = 2,2′:6′,2′′-terpyridine) onto the RuII-tpy and ZnII-bis(tpy) moiety. The visible absorption bands for Ru–Pt complexes are primarily due to RuII… read more here.
Keywords: tpy; two photon; heterometallic complexes; absorption ... See more keywords
Synthesis and reactivity of heterometallic complexes containing Mg- or Zn-metalloligands.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d1dt04117g
Abstract: Heteronuclear metal complexes comprising main group metals and transition metals have attracted widespread attention from researchers due to their applications in stoichiometric and catalytic activation of small molecules with possible cooperative effects. Herein, the advances… read more here.
Keywords: complexes containing; heterometallic complexes; reactivity heterometallic; synthesis reactivity ... See more keywords
Photo-generation of H2 by heterometallic complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01870e
Abstract: Multiple and different metals in a complex can accomplish single and sequential multi-step reactions, providing valuable procedures to obtain chemicals in one-pot synthetic routes. Biology has shown how cooperative catalysis is a powerful method for… read more here.
Keywords: photo generation; heterometallic complexes; generation heterometallic;
Heterometallic Cu(II)-M(II) (M = Mg, Ca and Sr) complexes with a N,O-donor ligand in situ generated from topiroxostat
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2020.1734189
Abstract: Abstract By introducing alkaline-earth metal ions (Mg2+, Ca2+, and Sr2+) as structure-directing agents, three new heterometallic complexes, Mg(H2O)6·[Cu2Mg(L)4(H2O)4]·4H2O (1), [CuCa(L)2(H2O)4]n (2) and [CuSr(L)2(H2O)4]n (3) [H2L = 4-(3-(pyridine-4-yl)-1H-1,2,4-triazol-5-yl)picolinic acid], have been synthesized under hydrothermal conditions and… read more here.
Keywords: donor ligand; heterometallic complexes; situ generated; h2o ... See more keywords
Structure and Properties of Heterometallics Based on Lanthanides and Transition Metals with Methoxy-β-Diketonates
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27238400
Abstract: The possibility of obtaining volatile polynuclear heterometallic complexes containing lanthanides and transition metals bound by methoxy-β-diketonates was studied. New compounds were prepared by cocrystallization of monometallic complexes from organic solvents. Ln(tmhd)3 were used as initial… read more here.
Keywords: heterometallic complexes; lanthanides transition; methoxy diketonates; dionate ... See more keywords
Sandwich d/f Heterometallic Complexes [(Ln(hfac)3)2M(acac)3] (Ln = La, Pr, Sm, Dy and M = Co; Ln = La and M = Ru)
Sign Up to like & getrecommendations! Published in 2024 at "Molecules"
DOI: 10.3390/molecules29163927
Abstract: Sandwich d/f heterometallic complexes [(Ln(hfac)3)2M(acac)3] (Ln = La, Pr, Sm, Dy and M = Co; Ln = La and M = Ru) were prepared in strictly anhydrous conditions reacting the formally unsaturated fragment [Ln(hfac)3] and… read more here.
Keywords: sandwich heterometallic; heterometallic complexes; complexes hfac; hfac acac ... See more keywords