Articles with "heterometallic coordination" as a keyword



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Solvothermal synthesis, structure and properties of heterometallic coordination polymer based on metalloligand and alkaline-earth metal calcium

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Published in 2019 at "Journal of Molecular Structure"

DOI: 10.1016/j.molstruc.2019.03.045

Abstract: Abstract A new 3D heterometallic coordination polymer (HCP), which formulated as {[Ca(H2O)2][LCo]·DMSO·2H2O}n (1) (DMSO = dimethyl sulfoxide), has been solvothermally synthesized from metalloligand LCo = [Co(2,4-pydca)2]2– (2,4-pydca = pyridine-2,4-dicarboxylate) and alkaline-earth ion CaII. HCP 1 has been well characterized by Fourier-transform… read more here.

Keywords: hcp; heterometallic coordination; structure; coordination polymer ... See more keywords
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Two heterometallic coordination polymers based on Sr(II) ion and dicarboxylate ligand

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Published in 2019 at "Polyhedron"

DOI: 10.1016/j.poly.2018.11.011

Abstract: Abstract Two new heterometallic coordination polymers(CPs) [ZnSr(pydc)2(H2O)6]n·2nH2O (1) and [CdSr(pydc)2(H2O)2]n (2) (H2pydc = pyridine-2,4-dicarboxylic acid) based on SrII ion and pyridine-2,4-dicarboxylate (H2pydc) have been solvothermally synthesized and characterized. Single crystal structure analysis shows that complex 1 is… read more here.

Keywords: dicarboxylate; ion; topology; coordination polymers ... See more keywords
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Na-Ln Heterometallic Coordination Polymers: Structure Modulation by Na+ Concentration and Efficient Detection to Tetracycline Antibiotics and 4-(Phenylazo)aniline.

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Published in 2021 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.1c00462

Abstract: On the basis of the lanthanide metalloligand [Ln(ODA)3]3- (H2ODA = oxydiacetic acid), three new Na-Ln heterometallic coordination polymers, [Ln(ODA)3Na2]n [Ln = Eu (1) and Gd (2)] and [Tb(ODA)3Na3(H2O)2]n (3), had been assembled by adjusting the… read more here.

Keywords: detection; heterometallic coordination; coordination polymers; phenylazo aniline ... See more keywords
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Ruthenium-Benzothiadiazole Building Block Derived Dynamic Heterometallic Ru-Ag Coordination Polymer and Its Enhanced Water-Splitting Feature.

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Published in 2021 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.1c00865

Abstract: This article deals with the development of the unprecedented redox-mediated heterometallic coordination polymer {[RuIII(acac)2(μ-bis-η1-N,η1-N-BTD)2AgI(ClO4)]ClO4}n (3) via the oxidation of the monomeric building block cis-[RuII(acac)2(η1-N-BTD)2] (1) by AgClO4 (BTD = exodentate 2,1,3-benzothiadiazole, acac = acetylacetonate). Monomeric… read more here.

Keywords: acac; ruii; water; heterometallic coordination ... See more keywords
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Luminescent 1D heterometallic (Ir,Cd) coordination polymers based on bis-cyclometalated Ir(III) metallatectons and trinuclear Cd(II) dianionic nodes.

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Published in 2021 at "Dalton transactions"

DOI: 10.1039/d0dt00822b

Abstract: Seven isostructural heterometallic luminescent (Ir,Cd) coordination polymers were prepared upon the combination of tris-chelate cationic Ir(III) complexes behaving as metalloligands with Cd(II) salts. Three octahedral Ir(III) complexes have been considered in the present report. They… read more here.

Keywords: coordination; luminescent heterometallic; polymers based; heterometallic coordination ... See more keywords
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Synthesis, Crystal Structure, and Photoluminescent Properties of a Series of LnIII–CuI Heterometallic Coordination Polymers Based on Cu4I3 Clusters and Ln–ina Rod Units

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Published in 2017 at "Australian Journal of Chemistry"

DOI: 10.1071/ch17076

Abstract: A novel series of LnIII–CuI heterometallic coordination polymers (HCPs) {[Ln2Cu4I3(ina)7(DMA)2]n·nDMA, Ln = La (1), Ce (2), Pr (3) Nd (4), Sm (5), Eu (6), Gd (7), Tb (8), Dy (9) Ho (10), Er (11), Yb (12), Hina = isonicotinic… read more here.

Keywords: lniii cui; cui heterometallic; heterometallic coordination; coordination polymers ... See more keywords