Photoelectron Velocity Map Imaging Spectroscopy of Heteronuclear Metal–Nickel Carbonyls MNi(CO)n− (M = Sc, Y; n = 2–6)
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DOI: 10.1007/s11244-017-0875-0
Abstract: The chemical bonding and electronic structure of heteronuclear metal–nickel carbonyls MNi(CO)n− (M = Sc, Y; n = 2–6) have been investigated by mass-selected photoelectron velocity map imaging spectroscopy and quantum chemical calculations. Two CO bonding modes (side-on-bonded and terminal… read more here.
Keywords: metal nickel; carbonyls; spectroscopy; heteronuclear metal ... See more keywords
Multiple CO2 reduction mediated by heteronuclear metal carbide cluster anions RhTaC2.
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DOI: 10.1039/d2dt01612e
Abstract: Noble metals dispersed on transition-metal carbides exhibit extraordinary activity in CO2 catalytic conversion and bimetallic carbides generated at the interface were proposed to contribute to the observed activity. Heteronuclear metal carbide clusters (HMCCs) that compositionally… read more here.
Keywords: metal carbide; co2 reduction; heteronuclear metal; co2 ... See more keywords
Mutual functionalization of dinitrogen and methane mediated by heteronuclear metal cluster anions CoTaC2−
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DOI: 10.1039/d2sc02416k
Abstract: The direct coupling of dinitrogen (N2) and methane (CH4) to construct the N–C bond is a fascinating but challenging approach for the energy-saving synthesis of N-containing organic compounds. Herein we identified a likely reaction pathway… read more here.
Keywords: 600 600; dinitrogen methane; metal cluster; heteronuclear metal ... See more keywords
Synthesis, Characterization and Antitumor Mechanism Investigation of Heterometallic Ru(Ⅱ)-Re(Ⅰ) Complexes
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DOI: 10.3389/fchem.2022.890925
Abstract: The development of heteronuclear metal complexes as potent anticancer agents has received increasing attention in recent years. In this study, two new heteronuclear Ru(Ⅱ)-Re(Ⅰ) metal complexes, [Ru(bpy)2LRe(CO)3(DIP)](PF6)3 and [Ru(phen)2LRe(CO)3(DIP)](PF6)3 [RuRe-1 and RuRe-2, L = 2-(4-pyridinyl)imidazolio[4,5-f][1,10]phenanthroline,… read more here.
Keywords: metal complexes; rure rure; heteronuclear metal; synthesis characterization ... See more keywords