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Published in 2019 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2019.06.088
Abstract: Abstract The C-centered bis(imidazol-1-yl)methane-based heteroscorpionate metal(II) complexes of the type [M(L1−3)Cl] (1–9), where M = Mn(II), Ni(II) or Cu(II) have been synthesized using the heteroscorpionate ligands, (2-hydroxyphenyl)bis(imidazol-1-yl)methane (HL1), (4-diethylamino-2-hydroxyphenyl)bis(imidazol-1-yl)methane (HL2) and (5-bromo-2-hydroxyphenyl)bis(imidazol-1-yl)methane (HL3). The spectral and theoretical…
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Keywords:
heteroscorpionate;
geometry;
imidazol methane;
bis imidazol ... See more keywords
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Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01645a
Abstract: Novel polynuclear helical aluminium complexes supported by bulky heteroscorpionate ligands have been developed and characterised. The use of bulkier ligands has allowed the isolation of unprecedented intermediates for the preparation of helical aluminium complexes. The…
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Keywords:
cyclic carbonates;
aluminium;
closing loop;
synthesis ... See more keywords