Articles with "heteroscorpionate" as a keyword



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Bis(imidazol-1-yl)methane-based heteroscorpionate metal(II) complexes: Theoretical, antimicrobial, antioxidant, in vitro cytotoxicity and c-Met tyrosine kinase studies

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Published in 2019 at "Journal of Molecular Structure"

DOI: 10.1016/j.molstruc.2019.06.088

Abstract: Abstract The C-centered bis(imidazol-1-yl)methane-based heteroscorpionate metal(II) complexes of the type [M(L1−3)Cl] (1–9), where M = Mn(II), Ni(II) or Cu(II) have been synthesized using the heteroscorpionate ligands, (2-hydroxyphenyl)bis(imidazol-1-yl)methane (HL1), (4-diethylamino-2-hydroxyphenyl)bis(imidazol-1-yl)methane (HL2) and (5-bromo-2-hydroxyphenyl)bis(imidazol-1-yl)methane (HL3). The spectral and theoretical… read more here.

Keywords: heteroscorpionate; geometry; imidazol methane; bis imidazol ... See more keywords
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Closing the loop in the synthesis of heteroscorpionate-based aluminium helicates: catalytic studies for cyclic carbonate synthesis.

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Published in 2022 at "Dalton transactions"

DOI: 10.1039/d2dt01645a

Abstract: Novel polynuclear helical aluminium complexes supported by bulky heteroscorpionate ligands have been developed and characterised. The use of bulkier ligands has allowed the isolation of unprecedented intermediates for the preparation of helical aluminium complexes. The… read more here.

Keywords: cyclic carbonates; aluminium; closing loop; synthesis ... See more keywords