Indazole-Derived Mono-/Diruthenium and Heterotrinuclear Complexes: Switchable Binding Mode, Electronic Form, and Anion Sensing Events.
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DOI: 10.1021/acs.inorgchem.2c02628
Abstract: The article deals with the newer classes of mononuclear: [(acac)2RuIII(H-Iz)(Iz-)] 1, [(acac)2RuIII(H-Iz)2]ClO4 [1]ClO4/[1']ClO4, and [(bpy)2RuII(H-Iz)(Iz-)]ClO4 [2]ClO4, mixed-valent unsymmetric dinuclear: [(acac)2RuIII(μ-Iz-)2RuII(bpy)2]ClO4 [3]ClO4, and heterotrinuclear: [(acac)2RuIII(μ-Iz-)2MII(μ-Iz-)2RuIII(acac)2] (M = Co:4a, Ni:4b, Cu:4c, and Zn:4d) complexes (H-Iz = indazole,… read more here.
Keywords: clo4; clo4 clo4; anion; acac 2ruiii ... See more keywords