Supramolecular encapsulation of hexaaquacobalt(II) cations in a hydrogen-bonded framework for slow magnetic relaxation and high proton conduction.
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DOI: 10.1039/d2dt03278c
Abstract: The supramolecular assembly of hexaaquacobalt(II) nitrate and a tetradentate carboxylate ligand resulted in the isolation of a cobalt hydrogen-bonded organic framework (HOF). Variable-temperature X-ray diffraction experiments reveal high thermal stability of the framework sustained by… read more here.
Keywords: high proton; hexaaquacobalt; framework; hydrogen ... See more keywords
Synthesis and structure of hexaaquacobalt bis(2-methyl-1H-imidazol-3-ium) tetraaquabis(benzene-1,3,5-tricarboxylato-κO)cobalt
Sign Up to like & getrecommendations! Published in 2022 at "Acta Crystallographica Section E: Crystallographic Communications"
DOI: 10.1107/s2056989022007046
Abstract: An hexaaquacobalt-based complex was synthesized and its structure determined by single-crystal X-ray diffraction. The observed Co—Ocarboxylate bond length is 2.0835 (9) Å and the Co—Owater bond lengths are in the range 2.0576 (9)-2.1196 (9) Å. read more here.
Keywords: structure; bis methyl; synthesis structure; hexaaquacobalt ... See more keywords