Hexaniobate Cluster Anion Monolayers on Gold Nanoparticles: A New Structural Role for Alkali Metal Countercations.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b03139
Abstract: Monolayer shells of polyoxotungstate cluster anions on gold nanoparticles in water were electrostatically stabilized by structurally integrated countercations, with formation constants, K, increasing in the order: Li+ < Na+ < K+ < TMA+ < Cs+… read more here.
Keywords: gold nanoparticles; alkali metal; hexaniobate cluster; new structural ... See more keywords
All-inorganic ferric wheel based on hexaniobate-anion linkers.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00971d
Abstract: Utilizing the inherent ability of Lindquist-type hexaniobate cluster-anions, [Nb6O19]8-, to serve as oxo-donor ligands in complexes with transition-metal cations, we report the synthesis and characterization of the first all-inorganic "ferric" wheel, Li48[(Nb6O19)8Fe8(OH)8]ยท88H2O, comprised of eight… read more here.
Keywords: inorganic ferric; hexaniobate cluster; wheel based; anion ... See more keywords