Charge-Separation-Type Ionic Crystals with Mixed AuI4CoIII2 and AuI4NiIICoIII Hexanuclear Complexes.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c00872
Abstract: Treatment of a digold(I) metalloligand, [AuI2(dppe)(d-Hpen)2] (H2LAu; d-H2pen = d-penicillamine, dppe = 1,2-bis(diphenylphosphino)ethane), with a 1:1 mixture of Co(OAc)2 and Ni(OAc)2 under aerobic conditions resulted in the formation of three types of hexanuclear complexes: [CoIII2(LAu)2]2+,… read more here.
Keywords: hexanuclear complexes; charge; separation type; charge separation ... See more keywords
Mixed-valence {FeII2FeIII4} hexanuclear complexes with thermally induced Fe(III) spin-crossover behavior.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt02041f
Abstract: Cyano-bridged mixed-valence {Fe6} hexanuclear complexes {[Tp4-MeFeII(CN)3]2[FeIII(Tpa)]2[FeIII(OR)(Tpa)]2}·6ClO4·S (Tp4-Me = tri(4-methyl-pyrazol-1-yl)borate, Tpa = tris(2-pyridylmethyl)amine; R = -CH3, S = 8MeOH 1, R = -C2H5, S = 6EtOH 2) have been obtained by building the units of [Tp4-MeFe(CN)3]-… read more here.
Keywords: feiii tpa; feiii; mixed valence; spin crossover ... See more keywords