A new mononuclear terbium and copper cocrystalline nitronyl nitroxide complex: synthesis, structure and magnetic properties
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2020.129012
Abstract: Abstract One 2p-3d-4f multispin complex [Cu(hfac)(4-Me-3-NITtrz)2][Tb(hfac)4]·H2O (1) has been obtained based on a functionalized nitronyl nitroxide radical 4-Me-3-Nit-trz (in which, 4-Me-3-Nit-trz = 2-[3-(4-methyl-l,2,4-triazolyl)]-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide, hfac = hexafluoroacetylacetone). Complex 1 crystallizes in tetragonal system, I 4 ¯ space group. The central… read more here.
Keywords: nitronyl nitroxide; terbium copper; new mononuclear; structure ... See more keywords
A Manganese (II) Dimer Bearing the Reduced Derivatives of Nitronyl Nitroxides
Sign Up to like & getrecommendations! Published in 2021 at "Polyhedron"
DOI: 10.1016/j.poly.2021.115427
Abstract: Abstract We report the synthesis, magnetic EPR and conducting properties of a new manganese complex [MnII(hfac)2(IMHPhOPh)]2[MnII(hfac)3](IMH2PhOPh) (1), containing the reduced forms (IMHPhOPh and IMH2PhOPh) of the NIT-PhOPh radical (NIT-PhOPh = 2,4‘-benzoxo-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide). Magnetic susceptibility studies reveal… read more here.
Keywords: mnii hfac; hfac imhphoph; dimer bearing; manganese dimer ... See more keywords
Mechanochemical Syntheses of Ln(hfac)3(H2O)x (Ln = La-Sm, Tb): Isolation of 10-, 9-, and 8-Coordinate Ln(hfac)n Complexes
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.2c01274
Abstract: Volatile lanthanide coordination complexes are critical to the generation of new optical and magnetic materials. One of the most common precursors for preparing volatile lanthanide complexes is the hydrate with the general formula Ln(hfac)3(H2O)x (x… read more here.
Keywords: hfac; syntheses hfac; spectroscopy; h2o isolation ... See more keywords
Position Assignment and Oxidation State Recognition of Fe and Co Centers in Heterometallic Mixed-Valent Molecular Precursors for the Low-Temperature Preparation of Target Spinel Oxide Materials.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b01032
Abstract: A series of mixed-valent, heterometallic (mixed-transition metal) diketonates that can be utilized as prospective volatile single-source precursors for the low-temperature preparation of MxM'3-xO4 spinel oxide materials is reported. Three iron-cobalt complexes with Fe/Co ratios of… read more here.
Keywords: temperature preparation; low temperature; coii hfac; coii ... See more keywords
Three-Dimensional Supramolecular Architectures with MnII Ions Assembled from Hydrogen Bonding Interactions: Crystal Structures and Antiferromagnetic Properties
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.1c05285
Abstract: Two novel cocrystal MnII compounds were successfully synthesized. The composition of two kinds crystals correspond to [Mn(hfac)2La2·Mn(hfac)2La(H2O)·Mn(hfac)2(H2O)2] (1) and [Mn(hfac)2Lb2·Mn(hfac)2(H2O)2·0.5(C6H14)] (2) [La = 1,3-bis(1′-oxyl-3′-oxido-4′,4′,5′,5′-tetramethyl-4,5-dihydro-1H-imidazol-2-y1)benzene; Lb = 1-(1′-oxyl-4′,4′,5′,5′-tetramethylimidazolin-2-yl)-3-(1′-oxyl-3′-oxo-4′,4′,5′,5′-tetramethylimidazolin-2-yl)benzene; hfac = hexafluoroacetylacetonato). Surprisingly, the compounds were not… read more here.
Keywords: hfac; mnii ions; architectures mnii; three dimensional ... See more keywords
Modulating the magnetization dynamics in Ln-Cu-Rad hetero-tri-spin complexes through cis/trans coordination of nitronyl nitroxide radicals around the metal center.
Sign Up to like & getrecommendations! Published in 2021 at "Dalton transactions"
DOI: 10.1039/d1dt00090j
Abstract: Self-assembling the novel nitronyl nitroxide radical NIT-3Py-5-Ph (2-(5-phenyl-3-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) with Ln(hfac)3·2H2O and Cu(hfac)2 (hfac = hexafluoroacetylacetonate) resulted in two heterometallic complexes with formula [LnCu(hfac)5(NIT-3Py-5-Ph)2] (Ln = Gd 1, Dy 2), in which two NIT-3Py-5-Ph radicals are… read more here.
Keywords: nitronyl nitroxide; nit 3py; 3py 4py; center ... See more keywords
Supramolecular heptanuclear Ln-Cu complexes involving nitronyl nitroxide biradicals: structure and magnetic behavior.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00220e
Abstract: Four novel heptanuclear Ln-Cu complexes with the formula [Ln2Cu(hfac)8(NITPhTzbis)2][LnCu(hfac)5(NITPhTzbis)]2 (LnCu = YCu 1, TbCu 2, DyCu 3 and HoCu 4; hfac = hexafluoroacetylacetonate) were successfully constructed by employing the triazole functionalized nitronyl nitroxide biradical ligand… read more here.
Keywords: hfac; hfac nitphtzbis; structure; supramolecular heptanuclear ... See more keywords
Formation and desorption of nickel hexafluoroacetylacetonate Ni(hfac)2 on a nickel oxide surface in atomic layer etching processes
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Vacuum Science and Technology"
DOI: 10.1116/6.0000293
Abstract: Thermal atomic layer etching (ALE) of nickel (Ni) may be performed with a step of thin-layer oxidation of its surface and another step of its removal by gas-phase hexafluoroacetylacetone (hfacH) as an etchant. In this… read more here.
Keywords: nickel; layer; surface; formation ... See more keywords
HFAC Dose Repetition and Accumulation Leads to Progressively Longer Block Carryover Effect in Rat Sciatic Nerve
Sign Up to like & getrecommendations! Published in 2022 at "Frontiers in Neuroscience"
DOI: 10.3389/fnins.2022.852166
Abstract: This paper describes high-frequency nerve block experiments carried out on rat sciatic nerves to measure the speed of recovery of A fibres from block carryover. Block carryover is the process by which nerve excitability remains… read more here.
Keywords: hfac; rat sciatic; block carryover; nerve ... See more keywords