Mechanochemical Syntheses of Ln(hfac)3(H2O)x (Ln = La-Sm, Tb): Isolation of 10-, 9-, and 8-Coordinate Ln(hfac)n Complexes
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DOI: 10.1021/acs.inorgchem.2c01274
Abstract: Volatile lanthanide coordination complexes are critical to the generation of new optical and magnetic materials. One of the most common precursors for preparing volatile lanthanide complexes is the hydrate with the general formula Ln(hfac)3(H2O)x (x… read more here.
Keywords: hfac; syntheses hfac; spectroscopy; h2o isolation ... See more keywords
Evidence of field induced slow magnetic relaxation in cis-[Co(hfac)2(H2O)2] exhibiting tri-axial anisotropy with a negative axial component.
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DOI: 10.1039/c7dt01236e
Abstract: We report a combined experimental characterization and theoretical modeling of the hexa-coordinated high-spin Co(ii) complex cis-[Co(hfac)2(H2O)2] (I). The magnetic static field (DC) data and EPR spectra (measurements were carried out on the powder samples of… read more here.
Keywords: field; component; hfac h2o; anisotropy ... See more keywords