Articles with "hfacac" as a keyword



Preconcentration of DNA using magnetic ionic liquids that are compatible with real-time PCR for rapid nucleic acid quantification

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Published in 2018 at "Analytical and Bioanalytical Chemistry"

DOI: 10.1007/s00216-018-1092-9

Abstract: AbstractNucleic acid extraction and purification represents a major bottleneck in DNA analysis. Traditional methods for DNA purification often require reagents that may inhibit quantitative polymerase chain reaction (qPCR) if not sufficiently removed from the sample.… read more here.

Keywords: extraction; enrichment factors; dna; hfacac ... See more keywords

Synthesis of a Palladium Dimer Supported by a C-Bound Trifluoroacetonate Bridge Formed by Cleavage of a Hexafluoroacetylacetonate Ligand

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Published in 2024 at "Organometallics"

DOI: 10.1021/acs.organomet.4c00263

Abstract: Palladium(II) hexafluoroacetylacetonate (Pd(Hfacac)2) is known to form adducts of bases, such as lutidine (2,6-dimethylpyridine). When treated with approximately 3 equiv of lutidine, Pd(Hfacac)2 yields a 1:1 complex as reported in the literature, Pd(O,O-Hfacac)(C-Hfacac)(lutidine), 1. However,… read more here.

Keywords: hfacac; hexafluoroacetylacetonate; ligand; trifluoroacetonate ... See more keywords

Multitopic 3,2′:6′,3′′-terpyridine ligands as 4-connecting nodes in two-dimensional 4,4-networks

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Published in 2022 at "Crystengcomm"

DOI: 10.1039/d2ce01130a

Abstract: The tetratopic 1,4-bis(2-phenylethoxy)-2,5-bis(3,2′:6′,3′′-terpyridin-4′-yl)benzene (1) and 1,4-bis(3-phenylpropoxy)-2,5-bis(3,2′:6′,3′′-terpyridin-4′-yl)benzene (2) ligands have been prepared and fully characterised. Combination of ligand 1 or 2 and [M(hfacac)2]·xH2O (M = Cu, x = 1; M = Zn, x = 2) under… read more here.

Keywords: bis; hfacac; multitopic terpyridine; terpyridine ligands ... See more keywords