HFO‐1234yf as a CF 3 ‐Building Block: Synthesis and Chemistry of CF 3 ‐Ynones
Sign Up to like & getrecommendations! Published in 2020 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.202001071
Abstract: Reaction of low cost, readily available 4th generation refrigerant gas 2,3,3,3‐tetrafluoropropene (HFO‐1234yf) with lithium diisopropylamide (LDA) leads to formation of lithium 3,3,3‐trifluoropropynide, addition of which to a range of aldehydes formed CF3‐alkynyl alcohol derivatives on… read more here.
Keywords: building block; block synthesis; chemistry; 1234yf building ... See more keywords
Kinetics, mechanism, and global warming potentials of HFO-1234yf initiated by O3 molecules and NO3 radicals: insights from quantum study
Sign Up to like & getrecommendations! Published in 2018 at "Environmental Science and Pollution Research"
DOI: 10.1007/s11356-018-2633-7
Abstract: In the present investigation, the oxidation of HFO-1234yf (2,3,3,3-tetrafluoropropene) with O3 molecule and NO3 radical is studied by quantum chemical methods. The possible reaction pathways of the titled molecule with O3 molecule and NO3 radical… read more here.
Keywords: molecule; potentials hfo; warming potentials; hfo 1234yf ... See more keywords
Kinetic mechanism of 2,3,3,3-tetrafluoropropene (HFO-1234yf) combustion
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Fluorine Chemistry"
DOI: 10.1016/j.jfluchem.2017.07.005
Abstract: Abstract A kinetic model for 2,3,3,3-tetrafluoropropene (HFO-1234yf) high temperature oxidation and combustion is proposed. It is combined with the GRI-Mech-3.0 model, the previously developed model for 2-bromo-3,3,3-trifluoropropene (2-BTP), and the NIST C 1 -C 2… read more here.
Keywords: maximum burning; combustion; tetrafluoropropene hfo; model ... See more keywords