Mechanically Robust Nafion‐Based Anhydrous Proton Exchange Membranes with High Proton Conductivity and Efficient In Situ Self‐Healing Capacities
Sign Up to like & getrecommendations! Published in 2025 at "Macromolecular Rapid Communications"
DOI: 10.1002/marc.202500291
Abstract: There is increasing demand for self‐healing high‐temperature proton exchange membranes (HT‐PEMs) with superior mechanical robustness and proton conductivity. In this study, the fabrication of mechanically robust HT‐PEMs (denoted as N‐IL‐PW) is demonstrated by integrating high… read more here.
Keywords: high proton; proton; self healing; proton conductivity ... See more keywords
High Proton Conductivity of Acid Impregnated COFs Stabilized by Post-Oxidation.
Sign Up to like & getrecommendations! Published in 2024 at "Small"
DOI: 10.1002/smll.202409238
Abstract: The investigation of proton conduction processes within artificial nanopores using phosphoric acid (H3PO4) and sulfuric acid (H2SO4) not only sheds light on the mechanisms of proton conduction for these strong acids in confined environments, while… read more here.
Keywords: cpof; high proton; proton; post ... See more keywords
A Heniconuclear {Mn21} Cluster-Based Coordination Polymer with Manganese(II) Linkers Showing High Proton Conductivity.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02441
Abstract: An unprecedented metal-linked cluster-based coordination polymer, composed of heniconuclear {Mn21} clusters and Mn(II) ions as the nodes and linkers, respectively, was self-assembled from a facile aqueous synthesis. The structural analysis reveals that the compound possesses… read more here.
Keywords: heniconuclear mn21; coordination polymer; high proton; based coordination ... See more keywords
High Water-Assisted Proton Conductivities of Two Cadmium(II) Complexes Constructed from Zwitterionic Ligands.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03445
Abstract: Finding more metal complexes with outstanding water stability and high proton conductivity still has important research significance for the energy field. Herein, two highly proton-conductive complexes, one hydrogen-bonded supramolecular framework (HSF) [Cd(CBIA)2(H2O)4]·2H2O (1) and one… read more here.
Keywords: proton conductivity; high proton; water; cbia ... See more keywords
Achieving High Proton Conductivity in MIL-91(Al) Aerogel.
Sign Up to like & getrecommendations! Published in 2024 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.4c00388
Abstract: The processability and sustainability of proton conductors are two important indicators of their application. Here, MIL-91(Al) with an intrinsic proton conduction framework originating from protonated phosphonate groups was cross-linked with poly(vinyl alcohol) (PVA) to obtain… read more here.
Keywords: mil aerogel; high proton; proton conductivity; proton ... See more keywords
High Proton Mobility with High Directionality in Isolated Channels of MOF-74.
Sign Up to like & getrecommendations! Published in 2018 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.8b11816
Abstract: Isolated one-dimensional (1-D) proton channels in a metal-organic framework, MOF-74, have been reasonably expected to show highly directional proton conductivity, although no evidence has been provided. As a result of dimensional anisotropy of the channels… read more here.
Keywords: proton mobility; mof; proton; high proton ... See more keywords
High proton conductivity in a nickel(ii) complex and its hybrid membrane.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c8dt04171g
Abstract: A novel nickel(ii) complex, [Ni(2,2'-bpy)3](H2SBTC)(H2O)5 (1) (2,2'-bpy = 2,2'-bipyridyl), was synthesized based on [Ni(2,2'-bpy)3]2+ discrete units and a partially deprotonated sulfonate-carboxylate ligand of H4SBTC (5-sulfonyl-1,2,4-benzentricarboxylic acid). The adjacent [Ni(2,2'-bpy)3]2+ cationic units were connected to H2SBTC2-… read more here.
Keywords: high proton; nickel complex; conductivity; proton conductivity ... See more keywords
Modulation of a coordination structure in a europium(III)-based metallo-supramolecular polymer for high proton conduction
Sign Up to like & getrecommendations! Published in 2018 at "RSC Advances"
DOI: 10.1039/c8ra07405d
Abstract: Developing high proton conducting solid materials is significant in the field of fuel cells. A europium(III)-based metallo-supramolecular polymer with uncoordinated carboxylic acids (PolyEu-H) was successfully synthesized by modifying the synthesis conditions. The proton conductivity was… read more here.
Keywords: polymer; proton; high proton; europium iii ... See more keywords
Post-synthesis functionalization of ZIF-90 with sulfonate groups for high proton conduction.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt02569h
Abstract: Introducing sulfonic acid groups into MOF materials is one of the effective approaches to enhance proton conduction. Here, we attempted to prepare a new post-modified ZIF-90-based material by addition reaction of the aldehyde group with… read more here.
Keywords: high proton; proton conduction; post synthesis; zif ... See more keywords
Supramolecular encapsulation of hexaaquacobalt(II) cations in a hydrogen-bonded framework for slow magnetic relaxation and high proton conduction.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt03278c
Abstract: The supramolecular assembly of hexaaquacobalt(II) nitrate and a tetradentate carboxylate ligand resulted in the isolation of a cobalt hydrogen-bonded organic framework (HOF). Variable-temperature X-ray diffraction experiments reveal high thermal stability of the framework sustained by… read more here.
Keywords: high proton; hexaaquacobalt; framework; hydrogen ... See more keywords
Cooperative defect engineering and ligand modification in UiO-66 to achieve high proton conductivity.
Sign Up to like & getrecommendations! Published in 2024 at "Chemical communications"
DOI: 10.1039/d4cc01414f
Abstract: D-UiO-66-NIM with high proton conductivity has been synthesized through the dual strategy of defect engineering and ligand modification. Moreover, D-UiO-66-NIM exhibits good temperature cycling stability and durability in proton conductivity. This work has developed a… read more here.
Keywords: high proton; defect engineering; proton; engineering ligand ... See more keywords