Stabilizing the High Spin Cobalt Atoms by Local Magnetic Asymmetry in p-Block Metals-Doped Spinel MnCo2O4 Catalysts for Efficient Oxygen Reduction.
Sign Up to like & getrecommendations! Published in 2025 at "Advanced materials"
DOI: 10.1002/adma.202513681
Abstract: Spinel MnCo2O4 (MCO) is often used for electrocatalytic oxygen reduction reaction (eORR), limited kinetically by the electronic spin state of surface cobalt (Co) centers. In this work, the rate‐determining step of eORR is unlocked by… read more here.
Keywords: oxygen reduction; high spin; spin; block metals ... See more keywords
Spin Excitations of High Spin Iron(II) in Metal–Organic Chains on Metal and Superconductor
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Science"
DOI: 10.1002/advs.202412351
Abstract: Many‐body interactions in metal–organic frameworks (MOFs) are fundamental for emergent quantum physics. Unlike their solution counterpart, magnetization at surfaces in low‐dimensional analogues is strongly influenced by magnetic anisotropy (MA) induced by the substrate and still… read more here.
Keywords: superconductor; spin excitations; iron; high spin ... See more keywords
High‐Spin States of Manganese(III) Enable Robust Cold‐Adapted Activity of MnO2 Nanozymes
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Science"
DOI: 10.1002/advs.202415477
Abstract: Developing novel cold‐adapted nanozymes and elucidating their mechanisms of action remains a great challenge. Inspired by natural oxidases that utilize high‐spin and high‐valent metal‐oxygen intermediates to achieve high efficiency at low temperatures, in this study,… read more here.
Keywords: mno2; high spin; cold adapted; cold ... See more keywords
Amorphous Engineering Driving d‐Orbital High Spin Configuration for Almost 100% 1O2‐Mediated Fenton‐Like Reactions
Sign Up to like & getrecommendations! Published in 2025 at "Advanced Science"
DOI: 10.1002/advs.202503665
Abstract: The inherent atomic disorder in amorphous materials leads to unsaturated atomic sites or dangling bonds, effectively modulating the material's electronic states and rendering it an ideal platform for the growth of single atoms. Herein, the… read more here.
Keywords: amorphous engineering; high spin; engineering driving; spin ... See more keywords
Structure and Bonding of High‐Spin Nitrosyl–Iron(II) Compounds with Mixed N,O‐Chelators and Aqua Ligands
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201601329
Abstract: High-spin nitrosyl-iron centres of the Enemark-Feltham {FeNO}(7) type exist in aqueous solution. Examples include the tentative brown-ring species [Fe(H2O)(5)(NO)](2+) and a tentative Fe-II/edta/NO species formed in the processes for scrubbing NO from flue-gas streams. Inert-gas… read more here.
Keywords: high spin; nitrosyl iron; chemistry; h2o ... See more keywords
High-Spin Nitrosyl–Iron(II) Compounds
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201700383
Abstract: Invited for the cover of this issue is the group of Peter Klufers from Ludwig-Maximilians-Universitat Munchen, Germany. The cover image shows a laboratory-scale bubble column, which was used for the nitrosation of a dissolved ferrous… read more here.
Keywords: high spin; nitrosyl iron; iron compounds; chemistry ... See more keywords
Bonding in the high spin lithium clusters: Non‐nuclear attractors play a crucial role
Sign Up to like & getrecommendations! Published in 2022 at "Journal of Computational Chemistry"
DOI: 10.1002/jcc.27056
Abstract: The bonding in lithium high‐spin clusters contradicts the usual chemical bonding concept since there are no electron pairs between the atoms, and they are bound with parallel spin electrons. Quantum theory of atoms in molecules… read more here.
Keywords: high spin; non nuclear; lithium; spin ... See more keywords
High spin Fe(III)-doped nanostructures as T1 MR imaging probes.
Sign Up to like & getrecommendations! Published in 2022 at "Wiley interdisciplinary reviews. Nanomedicine and nanobiotechnology"
DOI: 10.1002/wnan.1858
Abstract: Magnetic Resonance Imaging (MRI) T1 contrast agents based on Fe(III) as an alternative to Gd-based compounds have been under intense scrutiny in the last 6-8 years and a number of nanostructures have been designed and proposed… read more here.
Keywords: doped nanostructures; nanostructures imaging; high spin; spin iii ... See more keywords
A new high-spin iron(III) bis(aqua) complex with the meso-tetra(para-chlorophenyl)porphyrin: X-ray crystallography, Hirshfeld surface analysis, magnetic, EPR and electrochemical properties
Sign Up to like & getrecommendations! Published in 2018 at "Research on Chemical Intermediates"
DOI: 10.1007/s11164-018-3555-1
Abstract: Chemical preparation of the bis(aqua) iron(III) metalloporphyrin [FeIII(TClPP)(H2O)2](SO3CF3)·2(Pnz)·3/4(C6H12)·2H2O (TClPP = TClPP = 5,10,15,20-tetra(para-chlorophenyl)porphyrinato and Pnz = phenazine) coordination complex (I) was made. The crystal structure of (I) was determined by X-ray single-crystal diffraction and elucidated by Hirshfeld surface approach. Magnetic, spectroscopic… read more here.
Keywords: high spin; iron iii; hirshfeld surface;
High-Spin Sulfur-Mediated Phosphorous Activation Enables Safe and Fast Phosphorus Anodes for Sodium-Ion Batteries
Sign Up to like & getrecommendations! Published in 2020 at "Chem"
DOI: 10.1016/j.chempr.2019.10.021
Abstract: Summary Evaporation-condensation of red phosphorous to prepare phosphorous-based anodes inevitably generates white P residual, severely limiting its practical application due to the serious safety concern. Rather than removing the white P residual by complicated post-treatments,… read more here.
Keywords: high spin; mediated phosphorous; spin; sulfur ... See more keywords
Theoretical study on the reduction reactions from solid char(N): The effect of the nearby group and the high-spin state
Sign Up to like & getrecommendations! Published in 2019 at "Energy"
DOI: 10.1016/j.energy.2019.116286
Abstract: Abstract A fundamental understanding of the reduction reactions from solid char(N) is proposed with the aim of providing useful information to aid in minimising NOx emission. The direct reduction with (a) nearby radical; (b) nearby… read more here.
Keywords: state; reduction; high spin; reduction reactions ... See more keywords