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Published in 2024 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202405262
Abstract: Electrochemical water splitting offers an advancing approach to producing highly pure hydrogen and oxygen, motivated by the prevalence of a low‐carbon economy and the goal of a sustainable future. The customized modulation of electronic structures…
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Keywords:
valence doping;
water;
coses nas;
high valence ... See more keywords
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Published in 2025 at "Advanced Energy Materials"
DOI: 10.1002/aenm.202502935
Abstract: Electrochemical oxidation of 5‐hydroxymethylfurfural (HMF) using non‐precious transition metal catalysts presents a sustainable pathway for producing high‐value 2,5‐furandicarboxylic acid (FDCA). Manganese‐based materials hold promise for HMF oxidation reactions but suffer from low intrinsic conductivity and…
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Keywords:
valence active;
oxidation hydroxymethylfurfural;
high valence;
oxidation ... See more keywords
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Published in 2023 at "ChemPlusChem"
DOI: 10.1002/cplu.202200462
Abstract: Metal-organic framework (MOF) represents a new class of organic-inorganic hybrid microporous crystalline material. Owing to their high surface areas, tunable pore aperture, and rich functional groups, MOF materials have shown great promise in gas storage,…
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Keywords:
oxo cluster;
metal oxo;
valence mof;
high valence ... See more keywords
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Published in 2022 at "Small"
DOI: 10.1002/smll.202200303
Abstract: High-valence metal-doped multimetal (oxy)hydroxides outperform noble metal electrocatalysts for the oxygen evolution reaction (OER) owing to the modified energetics between 3d metals and high-valence dopants. However, the rational design of sufficient and subtle modulators is…
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Keywords:
nifecr ldh;
water;
operando high;
high valence ... See more keywords
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Published in 2018 at "Journal of Solid State Electrochemistry"
DOI: 10.1007/s10008-018-4046-4
Abstract: AbstractThe poor rate performance and low discharge capacity of LiCoO2 limit its applications. Therefore, in this work, we synthesized Li1-xMxCoO2 (M = Na, Zr, Nb) via solid-phase synthesis to improve its properties. X-ray diffraction (XRD)…
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Keywords:
capacity;
high valence;
licoo2;
rate ... See more keywords
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Published in 2020 at "Science China Materials"
DOI: 10.1007/s40843-020-1476-2
Abstract: Modulating the oxidation states of transition metal species has been regarded as a promising strategy to tune the redox activity and achieve more active sites in electrode materials. In this work, a unique three-dimensional (3D)…
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Keywords:
solid state;
high valence;
honeycomb like;
coxsy ... See more keywords
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Published in 2020 at "Nano Energy"
DOI: 10.1016/j.nanoen.2019.104333
Abstract: Abstract Molybdenum (Mo)-based transition metal oxides normally delivery superior energy density in lithium ion batteries through electrochemical conversion reactions. The main challenge for this kind of electrode material is to promote reversible transformation of Li2O…
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Keywords:
cobalt;
revealing activation;
high valence;
conversion ... See more keywords
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Published in 2025 at "Environmental science & technology"
DOI: 10.1021/acs.est.5c02622
Abstract: Advancing the catalytic oxidation of volatile organic compounds (VOCs) requires ongoingly boosting of both low-temperature activity and durability. Our strategy was to tailor suitable Cu-O-Mn coordination environments across numerous types of widely used CuMn bimetallic…
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Keywords:
catalytic oxidation;
valence;
tailoring dual;
high valence ... See more keywords
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Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b00104
Abstract: A-site-ordered layer-structured perovskite LaCa2Fe3O9 with unusually high valence Fe3.67+ was obtained by low-temperature topochemical oxidation of the A-site layer-ordered LaCa2Fe3O8. The unusually high valence Fe3.67+ in LaCa2Fe3O9 shows charge disproportionation of Fe3+ and Fe5+ first…
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Keywords:
charge ordering;
high valence;
charge;
valence fe3 ... See more keywords
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Published in 2021 at "Nano letters"
DOI: 10.1021/acs.nanolett.1c01581
Abstract: The high-valence metal catalysts show extraordinary talent in various electrochemical reactions. However, there is no facile method to synthesize high-valence noble metal-based materials. Herein, we synthesized the different high valence noble metal M-incorporated PdCu nanoparticles…
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Keywords:
water electrolysis;
high valence;
incorporated pdcu;
valence ... See more keywords
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Published in 2022 at "Nano letters"
DOI: 10.1021/acs.nanolett.2c01124
Abstract: Enhancing activity and stability of iridium- (Ir-) based oxygen evolution reaction (OER) catalysts is of great significance in practice. Here, we report a vacancy-rich nickel hydroxide stabilized Ir single-atom catalyst (Ir1-Ni(OH)2), which achieves long-term OER…
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Keywords:
oxygen evolution;
onto nickel;
oxygen;
high valence ... See more keywords