Synthesis, characterization, and reactivities of high valent metal–corrole (M = Cr, Mn, and Fe) complexes
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DOI: 10.1016/j.ccr.2019.213043
Abstract: Abstract For the first-row middle transition metals (Cr, Mn, and Fe), the formal oxidation states are relatively lower. However, biological systems in various enzymatic reactions rely extensively on the higher oxidation states of these first-row… read more here.
Keywords: oxidation; higher oxidation; metal; high valent ... See more keywords
Ion association with tetra-n-alkylammonium cations stabilizes higher-oxidation-state neptunium dioxocations
Sign Up to like & getrecommendations! Published in 2019 at "Nature Communications"
DOI: 10.1038/s41467-018-07982-5
Abstract: Extended-coordination sphere interactions between dissolved metals and other ions, including electrolyte cations, are not known to perturb the electrochemical behavior of metal cations in water. Herein, we report the stabilization of higher-oxidation-state Np dioxocations in… read more here.
Keywords: tetra alkylammonium; oxidation state; state neptunium; higher oxidation ... See more keywords