Highly chemoselective hydrogenation of lactone to diol over efficient copper-based bifunctional nanocatalysts
Sign Up to like & getrecommendations! Published in 2019 at "Applied Catalysis B: Environmental"
DOI: 10.1016/j.apcatb.2018.12.068
Abstract: Abstract Owing to the high economic values and broad applications of diols with various alkyl chains, the development of efficient heterogeneous catalysts for the highly chemoselective synthesis of diols is highly desirable. In this work,… read more here.
Keywords: highly chemoselective; mg1 5alo; cu1 mg1; hydrogenation ... See more keywords
Highly chemoselective reduction of azides to amines by Fe(0) nanoparticles in water at room temperature
Sign Up to like & getrecommendations! Published in 2017 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2017.07.076
Abstract: Abstract A highly chemoselective reduction of aryl, heteroaryl, acyl and sulfonyl azides to the corresponding amines has been achieved by Fe(0) nanoparticles in water at room temperature in the absence of external hydride source. Several… read more here.
Keywords: reduction; nanoparticles water; chemoselective reduction; water room ... See more keywords
Highly Chemoselective and Enantioselective Synthesis of 3,4-2H-Pyrindin-2-ones by an NHC-Catalyzed [3 + 3] Cyclization.
Sign Up to like & getrecommendations! Published in 2020 at "Organic letters"
DOI: 10.1021/acs.orglett.0c00699
Abstract: A highly chemoselective and enantioselective cyclization of γ-chloroenals and ketimines has been developed to synthesize enantiopure 3,4-2H-pyrindin-2-ones as major products. It is proposed that the intermediate enone IV reacted with an enamine to proceed with… read more here.
Keywords: cyclization; chemoselective enantioselective; pyrindin ones; highly chemoselective ... See more keywords
Highly Chemoselective Synthesis of Azaarene-Equipped CF3-Tertiary Alcohols under Metal-Free Conditions and Their Fungicidal Activities
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.2c05855
Abstract: A highly chemoselective reaction between α,β-unsaturated trifluoromethyl ketones with azaarenes under metal-free conditions was carried out, affording a range of valuable azaarene-equipped CF3-tertiary alcohols in moderate to excellent yields (up to 95% yield) with good… read more here.
Keywords: highly chemoselective; free conditions; metal free; cf3 tertiary ... See more keywords