Highly Fluorinated Interphase Enables the Exceptional Stability of Monolithic Al Foil Anode for Li‐Ion Batteries
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202316341
Abstract: Directly using aluminum (Al) foil as anode material offers a streamlined manufacturing process by eliminating the need for conductive additives, binders, and casting procedures. Nonetheless, monolithic Al foil anodes often suffer from mechanical failure and… read more here.
Keywords: interphase; foil anode; monolithic foil; foil ... See more keywords
Remodeling Highly Fluorinated Electrolyte via Shielding Agent Regulation toward Practical Lithium Metal Batteries
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Science"
DOI: 10.1002/advs.202404248
Abstract: Highly fluorinated electrolytes have proved effective in improving electrochemical stability of lithium metal batteries. However, excessive fluorination not only detrimentally impacts the electrolyte ionic conductivity, but also inevitably forms the over‐fluorinated interphases with sluggish ion… read more here.
Keywords: lithium metal; metal batteries; electrolyte; fluorinated electrolyte ... See more keywords
Highly fluorinated and hierarchical HNTs/SiO2 hybrid particles for substrate-independent superamphiphobic coatings
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2018.11.127
Abstract: Abstract In this study, superamphiphobic coatings were prepared using a spray-coating method based on highly fluorinated and hierarchical-structure halloysite nanotubes (HNTs)/SiO2 powder. The prepared superamphiphobic coatings could repel liquids with a surface tension as low… read more here.
Keywords: fluorinated hierarchical; superamphiphobic coatings; highly fluorinated; hnts sio2 ... See more keywords
Selective CO2 uptake mimics dissolution in highly fluorinated non-porous crystalline materials
Sign Up to like & getrecommendations! Published in 2025 at "Nature Chemistry"
DOI: 10.1038/s41557-025-01943-4
Abstract: Separation of CO2 from gas mixtures is important in applications such as CH4 gas purification and blue hydrogen production. Here we report selective CO2 uptake by a family of flexible silver coordination polymers (AgCPs) that… read more here.
Keywords: co2 uptake; non porous; co2; dissolution ... See more keywords
Electrochemical instability of highly fluorinated tetraphenyl borates and syntheses of their respective biphenyls.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc02996b
Abstract: Highly fluorinated tetraphenyl borate anions are of importance as weakly coordinating anions in metalorganic reactions. However, at high positive potentials their electrochemical stability in organic solvents is not sufficient. This was investigated by a comprehensive… read more here.
Keywords: electrochemical instability; tetraphenyl borates; fluorinated tetraphenyl; instability highly ... See more keywords
Highly fluorinated metal complexes as dual 19F and PARACEST imaging agents.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt01852b
Abstract: We reported a set of water-soluble transition metal complexes that can serve as both 19F and PARACEST magnetic resonance imaging agents. The high number of equivalent fluorine atoms and the paramagnetic effect of metals offer… read more here.
Keywords: imaging agents; metal complexes; fluorinated metal; 19f paracest ... See more keywords
Selective S-methylation of highly fluorinated thiocarbamates
Sign Up to like & getrecommendations! Published in 2017 at "Synthetic Communications"
DOI: 10.1080/00397911.2016.1245753
Abstract: ABSTRACT A series of new S-methyl O-fluoroalkyl N-alkyl(aryl)imidothiocarbonates were prepared by S-methylation of various fluoroalkylated thiocarbamates with methyl iodide in the presence of cesium carbonate and tetrabutylammonium iodide (TBAI) in tetrahydrofuran (THF) at room temperature.… read more here.
Keywords: methylation; fluorinated thiocarbamates; methylation highly; highly fluorinated ... See more keywords
Highly Fluorinated Barium Titanate Nanoparticle Dispersion for Fabrication of Lithographically Patterned Thin Films
Sign Up to like & getrecommendations! Published in 2019 at "Materials"
DOI: 10.3390/ma12244045
Abstract: We report the synthesis, characterization, and photopatterning of high-k inorganic nanoparticles that are covered with highly fluorinated carboxylic acid and, as a result, are solution-processable in fluorous liquids. Barium titanate (BTO) nanoparticles, 7–8 nm in… read more here.
Keywords: bto nanoparticles; barium titanate; thin films; highly fluorinated ... See more keywords