Highly reactive lanthanum doped zinc oxide nanofiber photocatalyst for effective decontamination of methyl parathion
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Materials Science: Materials in Electronics"
DOI: 10.1007/s10854-017-7125-x
Abstract: Polyacrylonitrile (PAN) nanofibers were produced using electrospinning technique and La doped ZnO Nanorods was immobilized to enhance photo catalytic activity for the decontamination of organo-phosphorous compounds. La doped ZnO nanorods were synthesized by hydrothermal method… read more here.
Keywords: highly reactive; lanthanum doped; decontamination; methyl parathion ... See more keywords
Synthesis and unusual photochemistry of a highly reactive pyrimidinedione
Sign Up to like & getrecommendations! Published in 2018 at "Mendeleev Communications"
DOI: 10.1016/j.mencom.2018.09.016
Abstract: The herein obtained 3-methyl-5,5-diphenylpyrimidine-2,4-(3H,5H)-dione forms upon photolysis an unusual bicyclic product, namely, 6-methyl-3,3,8,8-tetraphenyl-8,8a-dihydroimidazo[1.5-c]pyrimidine-5,7(3H,6H)-dione in 21% yield. The transformation starts with elimination of carbon monoxide and methyl isocyanate from the molecule of substrate via a ‘Type… read more here.
Keywords: highly reactive; unusual photochemistry; photochemistry highly; synthesis unusual ... See more keywords
Liquid coordination complexes as a new class of catalysts for the synthesis of highly reactive polyisobutylene
Sign Up to like & getrecommendations! Published in 2021 at "Polymer"
DOI: 10.1016/j.polymer.2021.123825
Abstract: Abstract A number of acidic liquid coordination complexes (LCC) based on phosphorus-containing electron donors such as tri-n-octylphosphine oxide (POct3O), triphenylphosphine oxide (PPh3O) or triphenylphoshine (PPh3), and Lewis acids (AlCl3, FeCl3, TiCl4) have been synthesized and… read more here.
Keywords: highly reactive; poct3o alcl3; reactive polyisobutylene; coordination complexes ... See more keywords
N-Sulfonyl acetylketenimine as a highly reactive intermediate for synthesis of N-Aroylsulfonamides
Sign Up to like & getrecommendations! Published in 2019 at "Tetrahedron"
DOI: 10.1016/j.tet.2018.12.005
Abstract: Abstract A highly reactive intermediate N-sulfonyl acetylketenimine was generated from an ynone-participated CuAAC/ring-opening method. Its unique structure allowed it to react with aryl carboxylic acids to give N-aroylsulfonamides via a novel Mumm-type rearrangement. read more here.
Keywords: highly reactive; acetylketenimine highly; intermediate synthesis; synthesis aroylsulfonamides ... See more keywords
Cell-Inspired Hydrogel Microcapsules with a Thin Oil Layer for Enhanced Retention of Highly Reactive Antioxidants.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.1c20748
Abstract: In nature, individual cells are compartmentalized by a membrane that protects the cellular elements from the surrounding environment while simultaneously equipped with an antioxidant defense system to alleviate the oxidative stress resulting from light, oxygen,… read more here.
Keywords: oil; enhanced retention; oil layer; highly reactive ... See more keywords
Highly Reactive Cyclic Carbonates with a Fused Ring toward Functionalizable and Recyclable Polycarbonates.
Sign Up to like & getrecommendations! Published in 2022 at "ACS macro letters"
DOI: 10.1021/acsmacrolett.1c00653
Abstract: Monomer design plays an important role in the development of polymers with desired thermal properties and chemical recyclability. Here we prepared a class of seven-membered ring carbonates containing trans-cyclohexyl fused rings. These monomers showed excellent… read more here.
Keywords: cyclic carbonates; reactive cyclic; ring toward; carbonates fused ... See more keywords
Preparation of Highly Reactive Lithium Metal Dendrites for the Synthesis of Organolithium Reagents.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c07207
Abstract: A long-standing problem in the area of organolithium chemistry has been the need for a highly reactive Li-metal source that mimics Li-powders but has the advantage of being freshly prepared from inexpensive and readily available… read more here.
Keywords: synthesis organolithium; preparation; organolithium reagents; metal ... See more keywords
Spectroscopic and DFT Characterization of a Highly Reactive Nonheme FeV-Oxo Intermediate.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b11400
Abstract: The reaction of [(PyNMe3)FeII(CF3SO3)2], 1, with excess peracetic acid at -40 °C generates a highly reactive intermediate, 2b(PAA), that has the fastest rate to date for oxidizing cyclohexane by a nonheme iron species. It exhibits… read more here.
Keywords: meo pynme3; highly reactive; spectroscopic dft; fev ... See more keywords
A Highly Reactive CoIII,IV2(μ-O)2 Diamond Core Complex that Cleaves C-H Bonds.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b09531
Abstract: The selective activation of strong sp3 C-H bonds at mild conditions is a key step in many biological and synthetic transformations, and an unsolved challenge for synthetic chemists. In nature, soluble methane monooxygenase (sMMO) is… read more here.
Keywords: coiii iv2; highly reactive; diamond; diamond core ... See more keywords
Highly reactive 2-deoxy-2-iodo-D-allo and D-gulo pyranosyl sulfoxide donors ensure β-stereoselective glycosylations with steroidal aglycones
Sign Up to like & getrecommendations! Published in 2018 at "RSC Advances"
DOI: 10.1039/c8ra06619a
Abstract: The preparation of well-defined D-xylo and D-ribo glycosides represents a synthetic challenge due to the limited configurational availability of starting materials and the laborious synthesis of homogeneous 2-deoxy-β-glycosidic linkages, in particular that of the sugar-steroid… read more here.
Keywords: highly reactive; reactive deoxy; deoxy iodo; steroidal aglycones ... See more keywords
In situ generation of highly reactive allenes from nitrocyclopropanes: controllable synthesis of enynes and enesters.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc01573g
Abstract: A new and efficient strategy for ring-opening reactions of nitrocyclopropanes is developed for the first time for the divergent synthesis of enynes and enesters via in situ generated highly reactive electron-deficient intermediate allenes. Controllable approaches… read more here.
Keywords: synthesis enynes; highly reactive; situ generation; enynes enesters ... See more keywords