Articles with "highly regio" as a keyword



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Highly regio- and stereoselective palladium-catalyzed allene bifunctionalization cascade via π-allyl intermediate

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Published in 2017 at "Tetrahedron"

DOI: 10.1016/j.tet.2017.08.021

Abstract: Abstract We report a palladium-catalyzed allene bifunctionalization reaction that forms C C and either C O or C N bonds in one pot with excellent regio- and stereoselectivity. Carboxylic acids, amides, and hydroxide are all… read more here.

Keywords: allene bifunctionalization; palladium catalyzed; highly regio; catalyzed allene ... See more keywords
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Highly Regio- and Stereoselective Intramolecular Rearrangement of Glycidol Acetal to Alkoxy Cyclic Acetals.

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Published in 2022 at "Organic letters"

DOI: 10.1021/acs.orglett.2c02397

Abstract: A new class of highly regio- and stereoselective intramolecular rearrangements of glycidol acetals to produce alkoxylated 1,3-dioxolane/1,3-dioxane is demonstrated. Selective Lewis acid activation of acetal generates an oxocarbenium ion that initiates the epoxide ring-opening event,… read more here.

Keywords: intramolecular rearrangement; rearrangement glycidol; glycidol acetal; regio stereoselective ... See more keywords
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Rhodium-Catalyzed Highly Regio- and Enantioselective Reductive Cyclization of Alkyne-Tethered Cyclohexadienones

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Published in 2018 at "ACS Catalysis"

DOI: 10.1021/acscatal.7b04054

Abstract: Rhodium-catalyzed asymmetric hydrogenation of alkyne-tethered cyclohexadienones enables highly regio- and enantioselective reductive cyclization to afford cis-hydrobenzofurans and cis-hydroindoles in high yields. Desymmetrization of 1,3-diyne-tethered cyclohexadienones was also explored, wherein the intramolecular coordination of a Rh… read more here.

Keywords: rhodium catalyzed; reductive cyclization; alkyne tethered; highly regio ... See more keywords
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Highly Regio- and Enantioselective Reductive Coupling of Alkynes and Aldehydes via Photoredox Cobalt Dual Catalysis.

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Published in 2021 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.1c03527

Abstract: A Co-catalyzed highly regio- and enantioselective reductive coupling of alkynes and aldehydes has been developed under visible light photoredox dual catalysis. A variety of enantioenriched allylic alcohols have been obtained by using unsymmetrical internal alkynes… read more here.

Keywords: regio enantioselective; enantioselective reductive; alkynes aldehydes; reductive coupling ... See more keywords
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Highly Regio- and Stereoselective Catalytic Synthesis of Conjugated Dienes and Polyenes.

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Published in 2018 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.8b05421

Abstract: Conjugated dienes and polyenes are typically synthesized by sequential introduction of C═C bonds. Here, we report a practical and scalable, catalytic dienylation that is highly regio- and stereoselective for both C═C bonds. The reaction is… read more here.

Keywords: conjugated dienes; dienes polyenes; stereoselective catalytic; regio stereoselective ... See more keywords
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Chiral cis-iron(ii) complexes with metal- and ligand-centered chirality for highly regio- and enantioselective alkylation of N-heteroaromatics†

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Published in 2019 at "Chemical Science"

DOI: 10.1039/c9sc04858h

Abstract: Iron-catalyzed highly regio- and enantioselective organic transformations with generality and broad substrate scope have profound applications in modern synthetic chemistry; an example is herein described based on cis-FeII complexes having metal- and ligand-centered chirality. The… read more here.

Keywords: cis; regio enantioselective; metal; highly regio ... See more keywords