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Published in 2017 at "Tetrahedron"
DOI: 10.1016/j.tet.2017.08.021
Abstract: Abstract We report a palladium-catalyzed allene bifunctionalization reaction that forms C C and either C O or C N bonds in one pot with excellent regio- and stereoselectivity. Carboxylic acids, amides, and hydroxide are all…
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Keywords:
allene bifunctionalization;
palladium catalyzed;
highly regio;
catalyzed allene ... See more keywords
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Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c02397
Abstract: A new class of highly regio- and stereoselective intramolecular rearrangements of glycidol acetals to produce alkoxylated 1,3-dioxolane/1,3-dioxane is demonstrated. Selective Lewis acid activation of acetal generates an oxocarbenium ion that initiates the epoxide ring-opening event,…
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Keywords:
intramolecular rearrangement;
rearrangement glycidol;
glycidol acetal;
regio stereoselective ... See more keywords
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Published in 2018 at "ACS Catalysis"
DOI: 10.1021/acscatal.7b04054
Abstract: Rhodium-catalyzed asymmetric hydrogenation of alkyne-tethered cyclohexadienones enables highly regio- and enantioselective reductive cyclization to afford cis-hydrobenzofurans and cis-hydroindoles in high yields. Desymmetrization of 1,3-diyne-tethered cyclohexadienones was also explored, wherein the intramolecular coordination of a Rh…
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Keywords:
rhodium catalyzed;
reductive cyclization;
alkyne tethered;
highly regio ... See more keywords
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Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c03527
Abstract: A Co-catalyzed highly regio- and enantioselective reductive coupling of alkynes and aldehydes has been developed under visible light photoredox dual catalysis. A variety of enantioenriched allylic alcohols have been obtained by using unsymmetrical internal alkynes…
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Keywords:
regio enantioselective;
enantioselective reductive;
alkynes aldehydes;
reductive coupling ... See more keywords
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Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b05421
Abstract: Conjugated dienes and polyenes are typically synthesized by sequential introduction of C═C bonds. Here, we report a practical and scalable, catalytic dienylation that is highly regio- and stereoselective for both C═C bonds. The reaction is…
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Keywords:
conjugated dienes;
dienes polyenes;
stereoselective catalytic;
regio stereoselective ... See more keywords
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Published in 2019 at "Chemical Science"
DOI: 10.1039/c9sc04858h
Abstract: Iron-catalyzed highly regio- and enantioselective organic transformations with generality and broad substrate scope have profound applications in modern synthetic chemistry; an example is herein described based on cis-FeII complexes having metal- and ligand-centered chirality. The…
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Keywords:
cis;
regio enantioselective;
metal;
highly regio ... See more keywords