Forging C–C Bonds with Hindered Nucleophiles and Carbonyl Electrophiles: Reactivity and Selectivity of Allylic Tin Reagents/n-BuLi
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DOI: 10.1021/acs.organomet.7b00765
Abstract: Under activation with n-BuLi, trialkylstannanes containing crotyl-, geranyl-, and phenyldienylmethyl appendages were reacted with efficiency and selectivity to various ketone and enone electrophiles with low reactivity. The straightforward process gives access to tertiary alcohols that… read more here.
Keywords: bonds hindered; forging bonds; nucleophiles carbonyl; reactivity ... See more keywords