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   Articles with "hmf" as a keyword



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A novel route for green conversion of cellulose to HMF by cascading enzymatic and chemical reactions

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recommendations! Published in 2017 at "Aiche Journal"

DOI: 10.1002/aic.15841

Abstract: In this work, a novel route to deconstruct cellulose into 5-hydroxymethylfurfural (HMF) by cascading enzymatic and chemical reactions is reported. For biocatalyst preparation, Fe3O4 nanoparticles encapsulated SBA-15 with appropriate pore size was synthesized and utilized… read more here.

Keywords: hmf cascading; novel route; conversion; chemical ... See more keywords
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Biocatalytic Reduction of HMF to 2,5-Bis(hydroxymethyl)furan by HMF-Tolerant Whole Cells.

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recommendations! Published in 2017 at "ChemSusChem"

DOI: 10.1002/cssc.201601426

Abstract: Catalytic upgrading of 5-hydroxymethylfurfural (HMF), an important biobased platform chemical for high-value products, is currently of great interest. In this work, a new highly HMFtolerant yeast strain-Meyerozyma guilliermondii SC1103 was isolated, and biocatalytic reduction of… read more here.

Keywords: reduction; reduction hmf; biocatalytic reduction; hmf ... See more keywords
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Electrochemical Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid (FDCA) in Acidic Media Enabling Spontaneous FDCA Separation.

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recommendations! Published in 2018 at "ChemSusChem"

DOI: 10.1002/cssc.201800532

Abstract: 2,5-Furandicarboxylic acid (FDCA) has become an increasingly desirable platform chemical to replace terephthalic acid in the production of a variety of polymeric materials, including polyethylene terephthalate. FDCA can be produced by the oxidation of 5-hydroxymethylfurfural… read more here.

Keywords: acidic media; oxidation; electrochemical oxidation; fdca ... See more keywords
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Fabrication of trifunctional polyoxometalate - decorating chitosan nanofibers in highly selective production of DFF from 5-HMF, fructose and glucose.

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recommendations! Published in 2019 at "ChemSusChem"

DOI: 10.1002/cssc.201901384

Abstract: Trifunctional polyoxometalate (POM) decorating chitosan nanofibers (H5PMo10V2O40/chitosan nanofibers, abbreviated as HPMoV/CS-f) had been synthesized using electrospinning method, which realized highly efficient oxidation of 5-hydroxymethylfurfural (5-HMF) to 2,5-diformylfuran (DFF). Decorating chitosan nanofibers by POMs generated enhanced… read more here.

Keywords: fructose glucose; trifunctional polyoxometalate; dff; chitosan nanofibers ... See more keywords
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Current Situation of the Challenging Scale‐Up Development of Hydroxymethylfurfural Production

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recommendations! Published in 2020 at "Chemsuschem"

DOI: 10.1002/cssc.202000581

Abstract: Abstract Hydroxymethylfurfural (HMF) is a high‐value platform chemical derived from renewable resources. In recent years, considerable efforts have been made to produce HMF also at industrial scale, which still faces some challenges regarding yield as… read more here.

Keywords: situation challenging; production; current situation; hmf ... See more keywords
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Crystal faces-tailored oxygen vacancy in Au/CeO2 catalysts for the efficient oxidation of HMF to FDCA.

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recommendations! Published in 2021 at "ChemSusChem"

DOI: 10.1002/cssc.202101983

Abstract: Developing an efficient catalyst to upgrade 5-hydroxymethylfurfural (HMF) to high value-added downstream chemicals is of great significance in biomass conversion. Three crystal-faces controllable nanorod (110)-, nanocube (100)- and nanooctaheron (111)- CeO2 supported Au nanoparticles have… read more here.

Keywords: oxygen; oxidation hmf; hmf; ceo2 ... See more keywords
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Selective conversion of HMF into 3-hydroxymethylcyclopentylamine through a one-pot cascade process in aqueous phase over bimetallic NiCo nanoparticles as catalyst.

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recommendations! Published in 2022 at "ChemSusChem"

DOI: 10.1002/cssc.202200194

Abstract: 5-hydroxymethylfurfural (HMF) has been successfully valorised into 3-hydroxymethyl cyclopentylamine through a one-pot cascade process in aqueous phase by coupling the hydrogenative ring-rearrangement of HMF into 3-hydroxymethylcyclopentanone (HCPN) followed by the reductive amination with ammonia. Mono… read more here.

Keywords: pot cascade; one pot; aqueous phase; hmf ... See more keywords
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Catalytic hydroconversion of 5-HMF to value-added chemicals: insights into the role of catalyst properties and feedstock purity.

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recommendations! Published in 2022 at "ChemSusChem"

DOI: 10.1002/cssc.202200412

Abstract: 5-hydroxymethylfurfural (HMF) is an important bio-derived platform molecule that is generally obtained from hexoses via acid-catalyzed dehydration. It can be effectively transformed into a variety of value-added derivatives thus being an ideal candidate for fossil… read more here.

Keywords: hydroconversion; purity; value added; catalytic hydroconversion ... See more keywords
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A light(er) approach for the selective HMF hydrogenation to BHMF without external H2: Nothing to sacrifice.

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recommendations! Published in 2022 at "ChemSusChem"

DOI: 10.1002/cssc.202200430

Abstract: The selective upconversion of 5-hydroxymethyfurfural (HMF), a biomass derived platform molecule to value added chemicals can ease the burden on petroleum based fine chemical synthesis. The active contribution of renewable energy sources along with low… read more here.

Keywords: hmf hydrogenation; selective hmf; hmf; light approach ... See more keywords
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Selective hydrogenation of HMF to 1-hydroxy-2,5-hexanedione by biochar supported Ru catalysts.

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recommendations! Published in 2022 at "ChemSusChem"

DOI: 10.1002/cssc.202200437

Abstract: The development of sustainable and efficient catalysts namely Ru supported activated biochars was carried out for the selective hydrogenation of 5-hydroxymethylfurfural (HMF) to 1-hydroxy-2,5-hexanedione (HHD). In particular, the activated biochars (A Lw and A HSw… read more here.

Keywords: hmf hydroxy; hydroxy hexanedione; hmf; selective hydrogenation ... See more keywords
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Current advances in the sustainable conversion of HMF into FDCA.

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recommendations! Published in 2022 at "ChemSusChem"

DOI: 10.1002/cssc.202200501

Abstract: 2,5-furandicarboxylic acid (FDCA) is currently considered one of the most relevant bio-sourced building blocks, representing a fully sustainable competitor for terephthalic acid as well as the main component in green polymers such as poly(ethylene 2,5-furandicarboxylate)… read more here.

Keywords: advances sustainable; hmf fdca; sustainable conversion; hmf ... See more keywords