A novel route for green conversion of cellulose to HMF by cascading enzymatic and chemical reactions
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DOI: 10.1002/aic.15841
Abstract: In this work, a novel route to deconstruct cellulose into 5-hydroxymethylfurfural (HMF) by cascading enzymatic and chemical reactions is reported. For biocatalyst preparation, Fe3O4 nanoparticles encapsulated SBA-15 with appropriate pore size was synthesized and utilized… read more here.
Keywords: hmf cascading; novel route; conversion; chemical ... See more keywords
Structure matching mechanism of nRu/FeCo2O4 for highly‐selective oxidation of HMF toward FDCA
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DOI: 10.1002/aic.18671
Abstract: The selective oxidation of 5‐hydroxymethylfurfural (HMF) toward 2,5‐furandicarboxylic acid (FDCA) offers a promising green pathway to obtain monomers for the synthesis of biodegradable plastics. However, developing a high‐selectivity catalyst and understanding the catalytic mechanism are… read more here.
Keywords: hmf toward; structure matching; hmf; oxidation ... See more keywords
Highly Efficient Electrooxidation of 5‐Hydroxymethylfurfural by NiCuP Supported on Porous Laser‐Induced Graphene
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DOI: 10.1002/cctc.202500229
Abstract: The electrooxidation of 5‐hydroxymethylfurfural (HMF) has emerged as a promising way to generate high‐value‐added bio‐based products. However, improving catalyst selectivity for HMF and inhibiting competitive oxygen evolution reaction (OER) in a limited potential range remain… read more here.
Keywords: catalyst; electrooxidation; porous laser; laser induced ... See more keywords
Self‐Supported Ru‐CoFe Prussian Blue Analogues for Selective and Scalable Electrooxidation of 5‐Hydroxymethylfurfural to 2,5‐Furandicarboxylic Acid
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DOI: 10.1002/cctc.202501428
Abstract: The electrochemical upgrading of biomass‐derived 5‐hydroxymethylfurfural (HMF) into 2,5‐furandicarboxylic acid (FDCA) represents a promising route for producing renewable monomers for biodegradable plastics. However, achieving high conversion and selectivity under industrially relevant conditions remains challenging due… read more here.
Keywords: prussian blue; hmf; cofe prussian; furandicarboxylic acid ... See more keywords
Biocatalytic Reduction of HMF to 2,5-Bis(hydroxymethyl)furan by HMF-Tolerant Whole Cells.
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DOI: 10.1002/cssc.201601426
Abstract: Catalytic upgrading of 5-hydroxymethylfurfural (HMF), an important biobased platform chemical for high-value products, is currently of great interest. In this work, a new highly HMFtolerant yeast strain-Meyerozyma guilliermondii SC1103 was isolated, and biocatalytic reduction of… read more here.
Keywords: reduction; reduction hmf; biocatalytic reduction; hmf ... See more keywords
Electrochemical Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid (FDCA) in Acidic Media Enabling Spontaneous FDCA Separation.
Sign Up to like & getrecommendations! Published in 2018 at "ChemSusChem"
DOI: 10.1002/cssc.201800532
Abstract: 2,5-Furandicarboxylic acid (FDCA) has become an increasingly desirable platform chemical to replace terephthalic acid in the production of a variety of polymeric materials, including polyethylene terephthalate. FDCA can be produced by the oxidation of 5-hydroxymethylfurfural… read more here.
Keywords: acidic media; oxidation; electrochemical oxidation; fdca ... See more keywords
Fabrication of trifunctional polyoxometalate - decorating chitosan nanofibers in highly selective production of DFF from 5-HMF, fructose and glucose.
Sign Up to like & getrecommendations! Published in 2019 at "ChemSusChem"
DOI: 10.1002/cssc.201901384
Abstract: Trifunctional polyoxometalate (POM) decorating chitosan nanofibers (H5PMo10V2O40/chitosan nanofibers, abbreviated as HPMoV/CS-f) had been synthesized using electrospinning method, which realized highly efficient oxidation of 5-hydroxymethylfurfural (5-HMF) to 2,5-diformylfuran (DFF). Decorating chitosan nanofibers by POMs generated enhanced… read more here.
Keywords: fructose glucose; trifunctional polyoxometalate; dff; chitosan nanofibers ... See more keywords
Current Situation of the Challenging Scale‐Up Development of Hydroxymethylfurfural Production
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DOI: 10.1002/cssc.202000581
Abstract: Abstract Hydroxymethylfurfural (HMF) is a high‐value platform chemical derived from renewable resources. In recent years, considerable efforts have been made to produce HMF also at industrial scale, which still faces some challenges regarding yield as… read more here.
Keywords: situation challenging; production; current situation; hmf ... See more keywords
Crystal faces-tailored oxygen vacancy in Au/CeO2 catalysts for the efficient oxidation of HMF to FDCA.
Sign Up to like & getrecommendations! Published in 2021 at "ChemSusChem"
DOI: 10.1002/cssc.202101983
Abstract: Developing an efficient catalyst to upgrade 5-hydroxymethylfurfural (HMF) to high value-added downstream chemicals is of great significance in biomass conversion. Three crystal-faces controllable nanorod (110)-, nanocube (100)- and nanooctaheron (111)- CeO2 supported Au nanoparticles have… read more here.
Keywords: oxygen; oxidation hmf; hmf; ceo2 ... See more keywords
Selective conversion of HMF into 3-hydroxymethylcyclopentylamine through a one-pot cascade process in aqueous phase over bimetallic NiCo nanoparticles as catalyst.
Sign Up to like & getrecommendations! Published in 2022 at "ChemSusChem"
DOI: 10.1002/cssc.202200194
Abstract: 5-hydroxymethylfurfural (HMF) has been successfully valorised into 3-hydroxymethyl cyclopentylamine through a one-pot cascade process in aqueous phase by coupling the hydrogenative ring-rearrangement of HMF into 3-hydroxymethylcyclopentanone (HCPN) followed by the reductive amination with ammonia. Mono… read more here.
Keywords: pot cascade; one pot; aqueous phase; hmf ... See more keywords
Catalytic hydroconversion of 5-HMF to value-added chemicals: insights into the role of catalyst properties and feedstock purity.
Sign Up to like & getrecommendations! Published in 2022 at "ChemSusChem"
DOI: 10.1002/cssc.202200412
Abstract: 5-hydroxymethylfurfural (HMF) is an important bio-derived platform molecule that is generally obtained from hexoses via acid-catalyzed dehydration. It can be effectively transformed into a variety of value-added derivatives thus being an ideal candidate for fossil… read more here.
Keywords: hydroconversion; purity; value added; catalytic hydroconversion ... See more keywords