HMNTA Complexes of Tetravalent Metal Ions: On the Roles of Carbonyl Oxygen and Amine Nitrogen in the Stabilization of Gas-Phase M(HMNTA)24+ Complexes.
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DOI: 10.1021/jasms.0c00420
Abstract: Gas-phase tetrapositively charged M(HMNTA)24+ (M = Zr, Hf, Th, and U) ions were generated via electrospray ionization of the M(ClO4)4 and N,N,N',N',N″,N″-hexamethylnitrilotriacetamide (HMNTA) mixtures in acetonitrile. In these complexes, the Zr4+, Hf4+, Th4+, and U4+… read more here.
Keywords: nitrogen; hmnta; carbonyl oxygen; hmnta complexes ... See more keywords