A Chemically Stable Hofmann-Type Metal-Organic Framework with Sandwich-Like Binding Sites for Benchmark Acetylene Capture.
Sign Up to like & getrecommendations! Published in 2020 at "Advanced materials"
DOI: 10.1002/adma.201908275
Abstract: The realization of porous materials for highly selective separation of acetylene (C2 H2 ) from various other gases (e.g., carbon dioxide and ethylene) by adsorption is of prime importance but challenging in the petrochemical industry.… read more here.
Keywords: hofmann type; chemically stable; type; stable hofmann ... See more keywords
Switchable Xe/Kr Selectivity in a Hofmann-Type Metal-Organic Framework via Temperature-Responsive Rotational Dynamics.
Sign Up to like & getrecommendations! Published in 2023 at "Small"
DOI: 10.1002/smll.202301905
Abstract: The development of adsorbents for Kr and Xe separation is essential to meet industrial demands and for energy conservation. Although a number of previous studies have focused on Xe-selective adsorbents, stimuli-responsive Xe/Kr-selective adsorbents still remain… read more here.
Keywords: temperature; hofmann type; selectivity; framework ... See more keywords
Two-Step Spin Crossover in Hofmann-Type Coordination Polymers [Fe(2-phenylpyrazine)2{M(CN)2}2] (M = Ag, Au).
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03302
Abstract: Two 2D Hofmann-type complexes of the composition [Fe(Phpz)2{M(CN)2}2] (where Phpz = 2-phenylpyrazine; M = Ag, Au) have been synthesized, and their spin-crossover (SCO) behavior has been thoroughly characterized. Single-crystal X-ray analysis reveals that these complexes… read more here.
Keywords: sco behavior; hofmann type; two step; spin crossover ... See more keywords
Tetrakis-Cyanoacetylides as Building Blocks for a Second Generation of Spin-Switchable Hofmann-type Networks with Enhanced Porosity
Sign Up to like & getrecommendations! Published in 2024 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.4c02732
Abstract: The combination of spin crossover (SCO) with guest incorporation properties has attracted the interest of researchers in the last couple of decades and has led to the design of numerous SCO porous coordination polymers (SCO-PCPs).… read more here.
Keywords: spin; tetrakis cyanoacetylides; type networks; hofmann type ... See more keywords