A Chemically Stable Hofmann-Type Metal-Organic Framework with Sandwich-Like Binding Sites for Benchmark Acetylene Capture.
Sign Up to like & getrecommendations! Published in 2020 at "Advanced materials"
DOI: 10.1002/adma.201908275
Abstract: The realization of porous materials for highly selective separation of acetylene (C2 H2 ) from various other gases (e.g., carbon dioxide and ethylene) by adsorption is of prime importance but challenging in the petrochemical industry.… read more here.
Keywords: hofmann type; chemically stable; type; stable hofmann ... See more keywords
Switchable Xe/Kr Selectivity in a Hofmann-Type Metal-Organic Framework via Temperature-Responsive Rotational Dynamics.
Sign Up to like & getrecommendations! Published in 2023 at "Small"
DOI: 10.1002/smll.202301905
Abstract: The development of adsorbents for Kr and Xe separation is essential to meet industrial demands and for energy conservation. Although a number of previous studies have focused on Xe-selective adsorbents, stimuli-responsive Xe/Kr-selective adsorbents still remain… read more here.
Keywords: temperature; hofmann type; selectivity; framework ... See more keywords
Two-Step Spin Crossover in Hofmann-Type Coordination Polymers [Fe(2-phenylpyrazine)2{M(CN)2}2] (M = Ag, Au).
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03302
Abstract: Two 2D Hofmann-type complexes of the composition [Fe(Phpz)2{M(CN)2}2] (where Phpz = 2-phenylpyrazine; M = Ag, Au) have been synthesized, and their spin-crossover (SCO) behavior has been thoroughly characterized. Single-crystal X-ray analysis reveals that these complexes… read more here.
Keywords: sco behavior; hofmann type; two step; spin crossover ... See more keywords