Cation-Directed Synthetic Strategy Using 4f Tungstoantimonates as Nonlacunary Precursors for the Generation of 3d–4f Clusters
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DOI: 10.1021/acs.inorgchem.0c00890
Abstract: The first synthetic pathway using a series of four nonlacunary 4f-heterometal-substituted polyoxotungstate clusters Na21[(Ln(H2O)(OH)2(CH3COO))3(WO4)(SbW9O33)3]·nH2O (NaLnSbW9; Ln = TbIII, DyIII, HoIII, ErIII, YIII) as precursors for the directed preparation of nine new 3d–4f heterometallic tungstoantimonates K5Na12H3[TM(H2O)Ln3(H2O)5(W3O11)(SbW9O33)3]·nH2O… read more here.
Keywords: tbiii dyiii; hoiii eriii; eriii yiii; spectroscopy ... See more keywords