Anion⋯anion self-assembly under the control of σ- and π-hole bonds.
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DOI: 10.1039/d3cs00479a
Abstract: The electrostatic attraction between charges of opposite signs and the repulsion between charges of the same sign are ubiquitous and influential phenomena in recognition and self-assembly processes. However, it has been recently revealed that specific… read more here.
Keywords: anion self; anion; hole bonds; anion anion ... See more keywords
The Formation of σ-Hole Bonds: A Physical Interpretation
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DOI: 10.3390/molecules29030600
Abstract: This paper discusses two quite different computational experiments relating to the formation of σ-hole bonds A···B. The first involves looking at the complex at equilibrium and finding the contour X of the electronic density which… read more here.
Keywords: formation hole; hole bonds; bonds physical; second experiment ... See more keywords