Structural and luminescent properties of homo- and heterometallic complexes of La, Li and Na with 2-(2-benzoxyazol-2-yl)phenolate ligands
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Luminescence"
DOI: 10.1016/j.jlumin.2018.06.046
Abstract: Abstract A series of homo and heterometallic La, Li and Na complexes with 2-(2-benzoxyazol-2-yl)phenolate (L) ligands were synthesized using La[N(SiMe3)2]3 and M[N(SiMe3)2] (M = Li, Na) or La(Cp)3 as starting materials for La2(L)6 (1), La2(L)6(bipy)… read more here.
Keywords: phenolate ligands; heterometallic complexes; homo heterometallic; complexes benzoxyazol ... See more keywords
Kinetic versus thermodynamic metalation enables synthesis of isostructural homo- and heterometallic trinuclear clusters.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical communications"
DOI: 10.1039/d0cc02346a
Abstract: Temperature-dependent metalation of the new hexadentate ligand (tris(5-(pyridin-2-yl)-1H-pyrrol-2-yl)methane; H3TPM) enables the selective synthesis of both mononuclear (i.e. Na(THF)4[Fe(TPM)], kinetic product) and trinuclear (i.e. Fe3(TPM)2, thermodynamic product) complexes. Exposure of Na(THF)4[Fe(TPM)] to FeCl2 or ZnCl2 triggers… read more here.
Keywords: versus thermodynamic; metalation; homo heterometallic; heterometallic trinuclear ... See more keywords