Homochiral diamond frameworks embedding helixes: Syntheses, structures and properties
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DOI: 10.1016/j.jssc.2019.120896
Abstract: Abstract A pair of homochiral metal−organic frameworks [Cd((R)-HCIA) (1,4-DMIB)]·xGuest (1-D; (R)-H3CIA=(R)-5-(1-carboxyethoxy)isophthalic acid, 1,4- DMIB=1,1'-(2,5-dimethyl-1,4-phenylene)bis(4-methyl-1H-imidazole)) and [Cd((S)- HCIA)(1,4-DMIB)]·xGuest (1-L) were formed from Cd2+, H3CIA and 1,4-DMIB under solvothermal conditions, respectively. X-ray crystallography reveals they are enantiomers… read more here.
Keywords: diamond frameworks; helixes syntheses; embedding helixes; homochiral diamond ... See more keywords