Homochiral metal‐organic frameworks based on amino acid ligands for HPLC separation of enantiomers
Sign Up to like & getrecommendations! Published in 2017 at "ELECTROPHORESIS"
DOI: 10.1002/elps.201700122
Abstract: Natural amino acids are well known to form coordination polymers with transition metal ions. In this study, six homochiral metal‐organic frameworks constructed from Zn2+ or Co2+ ions and various enantiopure amino acid (L‐tyrosine, L‐histidine, L‐tryptophan… read more here.
Keywords: separation enantiomers; amino acid; metal organic; metal ... See more keywords
Fabrication of Homochiral Metal-Organic Frameworks in TiO2 Nanochannels for In Situ Identification of 3,4-Dihydroxyphenylalanine Enantiomers.
Sign Up to like & getrecommendations! Published in 2021 at "Analytical chemistry"
DOI: 10.1021/acs.analchem.1c01903
Abstract: Enantioselective identification of chiral molecules is important for biomedical and pharmaceutical research. However, owing to identical molecular formulas and chemical properties of enantiomers, signal transduction and amplification are still the two major challenges in chiral… read more here.
Keywords: chiral recognition; metal organic; metal; identification ... See more keywords
Engineering UiO-68-Typed Homochiral Metal-Organic Frameworks for the Enantiomeric Separation of Fmoc-AAs and Mechanism Study.
Sign Up to like & getrecommendations! Published in 2023 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.3c01735
Abstract: Homochiral metal-organic frameworks (HMOFs) have been widely investigated in the application of enantiomeric separation. Nonetheless, it remains a significant challenge to explore the effect of multiple weak interactions between HMOF adsorbents and chiral adsorbates on… read more here.
Keywords: homochiral metal; fmoc; enantiomeric separation; separation ... See more keywords
Missing Linker Defects in a Homochiral Metal-Organic Framework: Tuning the Chiral Separation Capacity.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b10112
Abstract: Efficient chiral separation remains a very challenging task due to the identical physical and chemical properties of the enantiomers of a molecule. Enantiomers only behave differently from each other in the presence of other chiral… read more here.
Keywords: framework; metal organic; separation; acid ... See more keywords
Homochiral Metal-Organic Framework Based Mixed Matrix Membrane for Chiral Resolution
Sign Up to like & getrecommendations! Published in 2022 at "Membranes"
DOI: 10.3390/membranes12040357
Abstract: Efficient separation of enantiomers is critical in the chemical, pharmaceutical, and food industries. However, conventional separation methods, such as chromatography, crystallization, and enzymatic kinetic resolution, require high energy costs and specific reaction conditions for the… read more here.
Keywords: homochiral metal; mixed matrix; chiral resolution; matrix membrane ... See more keywords