Homocubane Chemistry: Synthesis and Structures of Mono- and Dicobaltaheteroborane Analogues of Tris- and Tetrahomocubanes
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DOI: 10.1021/acsomega.9b02568
Abstract: Room-temperature reactions between [Cp*CoCl]2 (Cp* = η5-C5Me5) and large excess of [BH2E3]Li (E = S or Se) led to the formation of homocubane derivatives, 1–7. These species are bimetallic tetrahomocubane, [(Cp*Co)2(μ-S)4(μ3-S)4B2H2], 1; bimetallic trishomocubane isomers,… read more here.
Keywords: homocubane chemistry; chemistry synthesis; structures mono; synthesis structures ... See more keywords