Homodinuclear Lanthanide Complexes with the Divergent Heterotopic 4,4′-BipyridineN-Oxide (bipyMO) Ligand
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DOI: 10.1002/ejic.201800747
Abstract: The synthesis of dinuclear molecular complexes [Eu2(dbm)6(bipyMO)2], 1, [Tb2(dbm)6(bipyMO)2], 2, [Eu2(tta)6(bipyMO)2], 3 [Eu2(hfac)6(bipyMO)3], 4, [Tb2(hfac)6(bipyMO)3], 5 is here reported (bipyMO = 4,4’bipyridine-N-oxide, Hdbm = dibenzoylmethane, Htta = thenoyltrifluoroacetone, Hhfac=hexafluoroacetylacetone). The products were obtained in mild… read more here.
Keywords: divergent heterotopic; lanthanide complexes; bipymo; complexes divergent ... See more keywords
Syntheses, structures and magnetic properties of macrocyclic Schiff base-supported homodinuclear lanthanide complexes.
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DOI: 10.1039/c8dt02243g
Abstract: Five new homodinuclear lanthanide complexes with the general formula [(acac)4Ln2(L)] (Ln3+ = Dy3+ (1), Tb3+ (2), Ho3+ (3), Er3+ (4), and Gd (5)) were synthesized by one-pot [2 + 2] condensation of 2,6-diformyl-4-methylphenol and 1,3-diaminopropane… read more here.
Keywords: structures magnetic; lanthanide complexes; magnetic properties; syntheses structures ... See more keywords