Development of a kinetic model of ethylene methoxycarbonylation with homogeneous Pd catalyst using a capillary microreactor
Sign Up to like & getrecommendations! Published in 2017 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2017.04.059
Abstract: The kinetics of gas-liquid methoxycarbonylation of ethylene using 0.0013 mol/L Pd(dtbpx)(dba) homogeneous catalyst at 100 °C and 10 bar were studied in a continuous flow Hastelloy capillary microreactor of 1 mm internal diameter. Characterisation of… read more here.
Keywords: capillary microreactor; methoxycarbonylation; model; homogeneous catalyst ... See more keywords
Surface-Seal Encapsulation of a Homogeneous Catalyst in a Mesoporous Metal-Organic Framework.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c11573
Abstract: A rapid surface sealing strategy has been developed for the encapsulation of a homogeneous catalyst, phosphotungstic acid (PTA), in a mesoporous metal-organic framework (MOF), MIL-101(Cr). This new surface polymerization method utilizes non-solvent-induced phase separation to… read more here.
Keywords: catalyst; surface; mesoporous metal; metal organic ... See more keywords