Homogeneous Manganese-Catalyzed Hydrofunctionalizations of Alkenes and Alkynes: Catalytic and Mechanistic Tendencies
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DOI: 10.1021/acsomega.2c05109
Abstract: In recent years, many manganese-based homogeneous catalytic precursors have been developed as powerful alternatives in organic synthesis. Among these, the hydrofunctionalizations of unsaturated C–C bonds correspond to outstanding ways to afford compounds with more versatile… read more here.
Keywords: manganese catalyzed; hydrofunctionalizations alkenes; mechanistic tendencies; homogeneous manganese ... See more keywords
Immobilizing a homogeneous manganese catalyst into MOF pores for α-alkylation of methylene ketones with alcohols.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt02629e
Abstract: Herein, for the first time, a metal-organic framework (MOF) is reported as a catalyst for α-alkylation of ketones with alcohols. Using an encapsulation strategy via nano-confinement of a homogeneous Mn-phenanthroline complex into MOF pores, functionalized… read more here.
Keywords: mof pores; manganese catalyst; mof; homogeneous manganese ... See more keywords