Alkyne Polymers from Stable Butatriene Homologues: Controlled Radical Polymerization of Vinylidenecyclopropanes.
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DOI: 10.1021/jacs.2c12220
Abstract: Controlled polymerization of cumulenic monomers represents a promising yet underdeveloped strategy toward well-defined alkyne polymers. Here we report a stereoelectronic effect-inspired approach using simple vinylidenecyclopropanes (VDCPs) as butatriene homologues in controlled radical ring-opening polymerizations. While… read more here.
Keywords: butatriene homologues; homologues controlled; alkyne polymers; controlled radical ... See more keywords