Ca2[Ti(HPO4)2(PO4)]·H2O, Ca[Ti2(H2O)(HPO3)4]·H2O, and Ti(H2PO2)3: Solid-State Oxidation via Proton-Coupled Electron Transfer.
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DOI: 10.1021/acs.inorgchem.1c02685
Abstract: Titanium phosphorus oxides (TiPOs) are promising energy-conversion materials, but most are of tetravalent titanium (TiIV), with the trivalent TiIIIPOs less explored because of instability and obstacles in synthesis. In this study, we used a simple… read more here.
Keywords: oxidation; hpo4 po4; hpo3 h2o; h2o ... See more keywords
Proton-Rich POM-Type K12Mo8O20(HPO4)8(PO4)Cl with Ion-Exchange Capabilities.
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DOI: 10.1021/acs.inorgchem.1c03822
Abstract: A proton-rich POM-type molybdenum phosphate K12Mo8O20(HPO4)8(PO4)Cl was successfully obtained. It crystallizes in a noncentrosymmetric tetragonal space group of P-4 (No. 81) with the unit cell parameters of a = 9.6580(4) Å, c = 14.2607(10) Å,… read more here.
Keywords: hpo4 po4; rich pom; pom type; proton rich ... See more keywords