Isolated molybdenum-based microporous POMs for selective adsorption of gases.
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DOI: 10.1039/d2dt00134a
Abstract: Dodecanuclear, icosanuclear and octanuclear porous MOF-like POM materials [MoV12O12(μ2-O)4(μ3-O)12(Htrz)4(trz)4]·nH2O (n = 22, 1; n = 92, 2; Htrz = 1H-1,2,3-triazole), [MoV8O8(μ2-O)12(Htrz)8]½·[MoV12O12(μ2-O)4(μ3-O)12(Htrz)4(trz)4]·44H2O (3), and [MoV8O8(μ2-O)12(Htrz)8]·62H2O (4) have been obtained and well characterized. Higher Mo12 agglomerates have… read more here.
Keywords: adsorption; htrz; isolated molybdenum; based microporous ... See more keywords