Asperemestrins A-D, Emestrin Hybrid Polymers with Bridged Skeletons from the Endophytic Fungus Aspergillus nidulans.
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DOI: 10.1021/acs.orglett.2c02701
Abstract: Four emestrin hybrid polymers, asperemestrins A-D (1-4, respectively), were isolated from the fungus Aspergillus nidulans. Asperemestrins A-C are the first examples of emestrin-sterigmatocystin heterodimers bearing a 7/5/6/6/5/5/6/6/6 nonacyclic system with a 2,5-diazabicyclo[2.2.2]octane-3,6-dione core, while asperemestrin… read more here.
Keywords: fungus aspergillus; hybrid polymers; asperemestrins emestrin; emestrin hybrid ... See more keywords
Neutral two-dimensional organometallic-organic hybrid polymers based on pentaphosphaferrocene, bipyridyl linkers and CuCl.
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DOI: 10.1039/c7dt04286h
Abstract: The reaction of the Pn ligand complex [Cp*Fe(η5-P5)] (1: Cp* = η5-C5Me5) with CuCl in the presence of 4,4'-bipyridine or 1,2-di(4-pyridyl)ethylene leads to the formation of three unprecedented neutral 2D organometallic-organic hybrid networks, the constitutional… read more here.
Keywords: hybrid polymers; dimensional organometallic; organic hybrid; two dimensional ... See more keywords
Influence of substituents in aryl groups on the structure, thermal transitions and electrorheological properties of zinc bis(diarylphosphate) hybrid polymers.
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DOI: 10.1039/d2dt00492e
Abstract: The structures and thermal properties of three new hybrid one-dimensional (1D) polymers based on zinc bis(diarylphosphate)s containing p-substituted phenyl rings are reported. The crystal structures of Zn[O2P(p-OC6H4NO2)2]2 (1), Zn[O2P(p-OC6H4OMe)2]2 (2) and Zn[O2P(p-OC6H4CO2Et)2]2 (3) differ from… read more here.
Keywords: hybrid polymers; influence substituents; bis diarylphosphate; zinc bis ... See more keywords