Insights into the hydrated electron generation from UV/aniline: Mechanism and quantum efficiency.
Sign Up to like & getrecommendations! Published in 2021 at "Chemosphere"
DOI: 10.1016/j.chemosphere.2021.132292
Abstract: The insight into the neglected reduction process accompanied by UV-based oxidation process may provide new ideas for the development of advanced oxidation and reduction technologies. In this study, aniline was comprehensively investigated as an unexpected… read more here.
Keywords: reduction; aniline; photolysis; quantum efficiency ... See more keywords
Scavenging of hydrated electron by HSA or Ligand/HSA adduct: Pulse radiolysis study
Sign Up to like & getrecommendations! Published in 2018 at "Radiation Physics and Chemistry"
DOI: 10.1016/j.radphyschem.2018.07.003
Abstract: Abstract The process of electron scavenging by molecule of human serum albumin in solution under neutral pH was studied. The rate constant of reaction eaq- with HSA is diffusion controlled (1.1 × 1010 dm3 mol−1). The transient… read more here.
Keywords: hsa; pulse radiolysis; site; hydrated electron ... See more keywords
Quantifying Hydrated Electron Transformation Kinetics in UV-Advanced Reduction Processes Using the Re-,UV Method.
Sign Up to like & getrecommendations! Published in 2022 at "Environmental science & technology"
DOI: 10.1021/acs.est.2c02003
Abstract: Ultraviolet advanced reduction processes (UV-ARP) have garnered significant attention recently for the degradation of several hard to treat contaminants, including recalcitrant per- and polyfluoroalkyl substances (PFAS). The rate of contaminant degradation in UV-ARP is directly… read more here.
Keywords: advanced reduction; hydrated electron; degradation; eaq ... See more keywords
Understanding the Temperature Dependence and Finite Size Effects in Ab Initio MD Simulations of the Hydrated Electron.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of chemical theory and computation"
DOI: 10.1021/acs.jctc.2c00335
Abstract: The hydrated electron is of interest to both theorists and experimentalists as a paradigm solution-phase quantum system. Although the bulk of the theoretical work studying the hydrated electron is based on mixed quantum/classical (MQC) methods,… read more here.
Keywords: simulations hydrated; chemistry; temperature; initio simulations ... See more keywords