Equilibrium and kinetic isotopic fractionation in the CO2 hydration and hydroxylation reactions: Analysis of the role of hydrogen-bonding via quantum mechanical calculations
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DOI: 10.1016/j.gca.2020.09.019
Abstract: Abstract The formation of H2CO3 and HCO3− from CO2 is common in aqueous environmental systems and occurs via the CO2 hydration and hydroxylation reactions. The reactions are especially important in the context of CaCO3 mineral… read more here.
Keywords: co2 hydration; fractionation; co2; hydration hydroxylation ... See more keywords