Recent advances in transfer hydration of nitriles with amides or aldoximes
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DOI: 10.1016/j.tetlet.2019.151557
Abstract: Abstract This digest paper focuses on recent developments in metal-catalyzed transfer hydration of nitriles to afford amides, using amides or aldoximes as water donors. Recent examples of applications in synthetic chemistry are also described. read more here.
Keywords: transfer hydration; hydration nitriles; amides aldoximes; recent advances ... See more keywords
Hydration of Nitriles Catalyzed by Ruthenium Complexes: Role of Dihydrogen Bonding Interactions in Promoting Base-Free Catalysis.
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DOI: 10.1021/acs.inorgchem.2c02058
Abstract: Ru(II) complexes of amide-phosphine-based tridentate ligands additionally containing pyridine, isoquinoline, and quinoline rings have been synthesized, and their catalytic utility for the selective hydration of nitriles to amides is explored under the base-containing as well… read more here.
Keywords: hydration nitriles; hydration; dihydrogen bonding; base free ... See more keywords
Selective Hydration of Nitriles to Corresponding Amides in Air with Rh(I)-N-Heterocyclic Complex Catalysts
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DOI: 10.3390/catal10010125
Abstract: A new synthetic method for obtaining [RhCl(cod)(NHC)] complexes (1–4) (cod = η4-1,5cyclooctadiene, NHC = N-heterocyclic carbene: IMes, SIMes, IPr, and SIPr, respectively) is reported together with the catalytic properties of 1–4 in nitrile hydration. In… read more here.
Keywords: catalysts selective; selective hydration; nitriles corresponding; hydration nitriles ... See more keywords