Half-sandwich hydrazine complexes of iridium: Preparation and reactivity
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DOI: 10.1016/j.ica.2017.04.016
Abstract: Abstract Chloro complexes IrCl2(η5-C5Me5)[P(OR)3] (1) (R Me, Et) were prepared by reacting dimer [IrCl2(η5-C5Me5)]2 with phosphites in alcohol. Treatment of 1 with R1NHNH2 gave monohydrazine complexes [IrCl(η5-C5Me5)(R1NHNH2){P(OR)3}]BPh4 (2, 3, 4) [R1 H (2), Me (3),… read more here.
Keywords: bph4; hydrazine complexes; c5me5 phn; c5me5 ... See more keywords
Pentamethylcyclopentadienyl half-sandwich hydrazine complexes of ruthenium: preparation and reactivity
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DOI: 10.1039/c8nj06019c
Abstract: The preparation and selective oxidation of hydrazine complexes of ruthenium stabilised by a pentamethylcyclopentadienyl fragment are described. The formation of the sandwich complex [Ru(η5-C5Me5)(η6-C6H6)]BPh4 through the oxidation of coordinate phenylhydrazine is also reported. read more here.
Keywords: complexes ruthenium; hydrazine complexes; preparation; pentamethylcyclopentadienyl half ... See more keywords