Domino Sequences Involving Stereoselective Hydrazone-Type Heck Reaction and Denitrogenative [1,5]-Sigmatropic Rearrangement.
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DOI: 10.1021/jacs.3c01075
Abstract: Although the Heck reactions of alkene partners with various electrophiles have achieved great success, the variant focused on carbonāheteroatom counterparts still remains elusive. Herein, we report a Pd(0)-catalyzed asymmetric intramolecular hydrazone-type Heck reaction of N-[(Z)-3-iodoallyl]-aminoacetaldehyde… read more here.
Keywords: heck; heck reaction; hydrazone; denitrogenative sigmatropic ... See more keywords