An Electrochemical Way to Generate Amphiphiles from Hydrazones for the Synthesis of 1,2,4‐Triazole Scaffold Cyclic Compounds
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DOI: 10.1002/open.202100268
Abstract: Abstract An electro‐oxidative cyclization pathway in which hydrazones are selected as starting materials to generate amphiphiles by reacting with benzylamines and benzamides was reported. This strategy successfully prepared a series of 1,2,4‐triazoles in satisfactory yields.… read more here.
Keywords: hydrazones synthesis; way generate; electrochemical way; generate amphiphiles ... See more keywords
Copper(I)-Catalyzed Oxyamination of β,γ-Unsaturated Hydrazones: Synthesis of Dihydropyrazoles.
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DOI: 10.1021/acs.orglett.9b02733
Abstract: An efficient aerobic copper(I)-catalyzed oxyamination of β,γ-unsaturated hydrazones has been developed. The methodology provides effective access to dihydropyrazole derivatives in a one-pot process utilizing dioxygen as a sustainable sacrificial oxidant. Mechanistic studies have been performed… read more here.
Keywords: oxyamination unsaturated; hydrazones synthesis; copper catalyzed; catalyzed oxyamination ... See more keywords