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   Articles with "hydricity" as a keyword



Enhanced Excited-State Hydricity of Pd-H Allows for Unusual Head-to-Tail Hydroalkenylation of Alkenes.

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recommendations! Published in 2023 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.3c02410

Abstract: Photoinduced enhancement of hydricity of palladium hydride species enables unprecedented hydride addition-like ("hydridic") hydropalladation of electron-deficient alkenes, which allows for chemoselective head-to-tail cross-hydroalkenylation of electron-deficient and electron-rich alkenes. This mild and general protocol works with… read more here.

Keywords: head tail; hydroalkenylation; hydricity; enhanced excited ... See more keywords

Reversible Interfacial Hydride Transfer as a Complementary Tool To Measure Molecular Hydricity.

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recommendations! Published in 2025 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.5c09582

Abstract: Hydride transfer is an essential elementary reaction across the chemical value chain, but there are limited methods available for quantifying thermodynamic hydricity (ΔGH-), particularly among main group reagents. Herein, we exploit facile H2 activation and… read more here.

Keywords: complementary tool; hydride transfer; hydricity; hydride ... See more keywords

Thermodynamic Hydricity of [FeFe]-Hydrogenases.

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recommendations! Published in 2019 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.8b13084

Abstract: After remaining elusive for many years, terminal hydride states have now been identified in several native and mutant [FeFe]-hydrogenases. In this Perspective, hydride states of [FeFe]-hydrogenases are considered on the basis of hydricity, a thermodynamic… read more here.

Keywords: hydride; fefe hydrogenases; hydricity; thermodynamic hydricity ... See more keywords

Metal- and ligand-substitution-induced changes in the kinetics and thermodynamics of hydrogen activation and hydricity in a dinuclear metal complex.

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recommendations! Published in 2024 at "Dalton transactions"

DOI: 10.1039/d4dt00361f

Abstract: Catalytic function in organometallic complexes is achieved by carefully selecting their central metals and ligands. In this study, the effects of a metal and a ligand on the kinetics and thermodynamics of hydrogen activation, hydricity… read more here.

Keywords: hydricity; thermodynamics; hydrogen activation; metal ligand ... See more keywords