Enhanced Excited-State Hydricity of Pd-H Allows for Unusual Head-to-Tail Hydroalkenylation of Alkenes.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c02410
Abstract: Photoinduced enhancement of hydricity of palladium hydride species enables unprecedented hydride addition-like ("hydridic") hydropalladation of electron-deficient alkenes, which allows for chemoselective head-to-tail cross-hydroalkenylation of electron-deficient and electron-rich alkenes. This mild and general protocol works with… read more here.
Keywords: head tail; hydroalkenylation; hydricity; enhanced excited ... See more keywords
Thermodynamic Hydricity of [FeFe]-Hydrogenases.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b13084
Abstract: After remaining elusive for many years, terminal hydride states have now been identified in several native and mutant [FeFe]-hydrogenases. In this Perspective, hydride states of [FeFe]-hydrogenases are considered on the basis of hydricity, a thermodynamic… read more here.
Keywords: hydride; fefe hydrogenases; hydricity; thermodynamic hydricity ... See more keywords